First experimental evidence of the piezoelectric nature of struvite

Abstract In this paper, we present the first experimental evidence of the piezoelectric nature of struvite (MgNH4PO4·6H2O). Using a single diffusion gel growth technique, we have grown struvite crystals in the form of plane parallel plates. For struvite crystals of this shape, we measured the piezoe...

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Autores principales: Jolanta Prywer, Rafał Kruszyński, Marcin Świątkowski, Andrzej Soszyński, Dariusz Kajewski, Krystian Roleder
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Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/69875318dd244a6485b2e03929981ed7
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spelling oai:doaj.org-article:69875318dd244a6485b2e03929981ed72021-12-02T16:26:23ZFirst experimental evidence of the piezoelectric nature of struvite10.1038/s41598-021-94410-22045-2322https://doaj.org/article/69875318dd244a6485b2e03929981ed72021-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-94410-2https://doaj.org/toc/2045-2322Abstract In this paper, we present the first experimental evidence of the piezoelectric nature of struvite (MgNH4PO4·6H2O). Using a single diffusion gel growth technique, we have grown struvite crystals in the form of plane parallel plates. For struvite crystals of this shape, we measured the piezoelectric coefficients d 33 and d 32. We have found that at room temperature the value of piezoelectric coefficient d 33 is 3.5 pm/V, while that of d 32 is 4.7 pm/V. These values are comparable with the values for other minerals. Struvite shows stable piezoelectric properties up to the temperature slightly above 350 K, for the heating rate of 0.4 K/min. For this heating rate, and above this temperature, the thermal decomposition of struvite begins, which, consequently, leads to its transformation into dittmarite with the same non-centrosymmetric symmetry as in case of struvite. The struvite-dittmarite transformation temperature is dependent on the heating rate. The higher the heating rate, the higher the temperature of this transformation. We have also shown that dittmarite, like struvite exhibits piezoelectric properties.Jolanta PrywerRafał KruszyńskiMarcin ŚwiątkowskiAndrzej SoszyńskiDariusz KajewskiKrystian RolederNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Jolanta Prywer
Rafał Kruszyński
Marcin Świątkowski
Andrzej Soszyński
Dariusz Kajewski
Krystian Roleder
First experimental evidence of the piezoelectric nature of struvite
description Abstract In this paper, we present the first experimental evidence of the piezoelectric nature of struvite (MgNH4PO4·6H2O). Using a single diffusion gel growth technique, we have grown struvite crystals in the form of plane parallel plates. For struvite crystals of this shape, we measured the piezoelectric coefficients d 33 and d 32. We have found that at room temperature the value of piezoelectric coefficient d 33 is 3.5 pm/V, while that of d 32 is 4.7 pm/V. These values are comparable with the values for other minerals. Struvite shows stable piezoelectric properties up to the temperature slightly above 350 K, for the heating rate of 0.4 K/min. For this heating rate, and above this temperature, the thermal decomposition of struvite begins, which, consequently, leads to its transformation into dittmarite with the same non-centrosymmetric symmetry as in case of struvite. The struvite-dittmarite transformation temperature is dependent on the heating rate. The higher the heating rate, the higher the temperature of this transformation. We have also shown that dittmarite, like struvite exhibits piezoelectric properties.
format article
author Jolanta Prywer
Rafał Kruszyński
Marcin Świątkowski
Andrzej Soszyński
Dariusz Kajewski
Krystian Roleder
author_facet Jolanta Prywer
Rafał Kruszyński
Marcin Świątkowski
Andrzej Soszyński
Dariusz Kajewski
Krystian Roleder
author_sort Jolanta Prywer
title First experimental evidence of the piezoelectric nature of struvite
title_short First experimental evidence of the piezoelectric nature of struvite
title_full First experimental evidence of the piezoelectric nature of struvite
title_fullStr First experimental evidence of the piezoelectric nature of struvite
title_full_unstemmed First experimental evidence of the piezoelectric nature of struvite
title_sort first experimental evidence of the piezoelectric nature of struvite
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/69875318dd244a6485b2e03929981ed7
work_keys_str_mv AT jolantaprywer firstexperimentalevidenceofthepiezoelectricnatureofstruvite
AT rafałkruszynski firstexperimentalevidenceofthepiezoelectricnatureofstruvite
AT marcinswiatkowski firstexperimentalevidenceofthepiezoelectricnatureofstruvite
AT andrzejsoszynski firstexperimentalevidenceofthepiezoelectricnatureofstruvite
AT dariuszkajewski firstexperimentalevidenceofthepiezoelectricnatureofstruvite
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