First experimental evidence of the piezoelectric nature of struvite
Abstract In this paper, we present the first experimental evidence of the piezoelectric nature of struvite (MgNH4PO4·6H2O). Using a single diffusion gel growth technique, we have grown struvite crystals in the form of plane parallel plates. For struvite crystals of this shape, we measured the piezoe...
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2021
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oai:doaj.org-article:69875318dd244a6485b2e03929981ed72021-12-02T16:26:23ZFirst experimental evidence of the piezoelectric nature of struvite10.1038/s41598-021-94410-22045-2322https://doaj.org/article/69875318dd244a6485b2e03929981ed72021-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-94410-2https://doaj.org/toc/2045-2322Abstract In this paper, we present the first experimental evidence of the piezoelectric nature of struvite (MgNH4PO4·6H2O). Using a single diffusion gel growth technique, we have grown struvite crystals in the form of plane parallel plates. For struvite crystals of this shape, we measured the piezoelectric coefficients d 33 and d 32. We have found that at room temperature the value of piezoelectric coefficient d 33 is 3.5 pm/V, while that of d 32 is 4.7 pm/V. These values are comparable with the values for other minerals. Struvite shows stable piezoelectric properties up to the temperature slightly above 350 K, for the heating rate of 0.4 K/min. For this heating rate, and above this temperature, the thermal decomposition of struvite begins, which, consequently, leads to its transformation into dittmarite with the same non-centrosymmetric symmetry as in case of struvite. The struvite-dittmarite transformation temperature is dependent on the heating rate. The higher the heating rate, the higher the temperature of this transformation. We have also shown that dittmarite, like struvite exhibits piezoelectric properties.Jolanta PrywerRafał KruszyńskiMarcin ŚwiątkowskiAndrzej SoszyńskiDariusz KajewskiKrystian RolederNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021) |
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Medicine R Science Q Jolanta Prywer Rafał Kruszyński Marcin Świątkowski Andrzej Soszyński Dariusz Kajewski Krystian Roleder First experimental evidence of the piezoelectric nature of struvite |
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Abstract In this paper, we present the first experimental evidence of the piezoelectric nature of struvite (MgNH4PO4·6H2O). Using a single diffusion gel growth technique, we have grown struvite crystals in the form of plane parallel plates. For struvite crystals of this shape, we measured the piezoelectric coefficients d 33 and d 32. We have found that at room temperature the value of piezoelectric coefficient d 33 is 3.5 pm/V, while that of d 32 is 4.7 pm/V. These values are comparable with the values for other minerals. Struvite shows stable piezoelectric properties up to the temperature slightly above 350 K, for the heating rate of 0.4 K/min. For this heating rate, and above this temperature, the thermal decomposition of struvite begins, which, consequently, leads to its transformation into dittmarite with the same non-centrosymmetric symmetry as in case of struvite. The struvite-dittmarite transformation temperature is dependent on the heating rate. The higher the heating rate, the higher the temperature of this transformation. We have also shown that dittmarite, like struvite exhibits piezoelectric properties. |
format |
article |
author |
Jolanta Prywer Rafał Kruszyński Marcin Świątkowski Andrzej Soszyński Dariusz Kajewski Krystian Roleder |
author_facet |
Jolanta Prywer Rafał Kruszyński Marcin Świątkowski Andrzej Soszyński Dariusz Kajewski Krystian Roleder |
author_sort |
Jolanta Prywer |
title |
First experimental evidence of the piezoelectric nature of struvite |
title_short |
First experimental evidence of the piezoelectric nature of struvite |
title_full |
First experimental evidence of the piezoelectric nature of struvite |
title_fullStr |
First experimental evidence of the piezoelectric nature of struvite |
title_full_unstemmed |
First experimental evidence of the piezoelectric nature of struvite |
title_sort |
first experimental evidence of the piezoelectric nature of struvite |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/69875318dd244a6485b2e03929981ed7 |
work_keys_str_mv |
AT jolantaprywer firstexperimentalevidenceofthepiezoelectricnatureofstruvite AT rafałkruszynski firstexperimentalevidenceofthepiezoelectricnatureofstruvite AT marcinswiatkowski firstexperimentalevidenceofthepiezoelectricnatureofstruvite AT andrzejsoszynski firstexperimentalevidenceofthepiezoelectricnatureofstruvite AT dariuszkajewski firstexperimentalevidenceofthepiezoelectricnatureofstruvite AT krystianroleder firstexperimentalevidenceofthepiezoelectricnatureofstruvite |
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1718384056531419136 |