Hydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil
The zeolite Y had been successfully modified by HCl and/or NaOH treatment. The modification of zeolite Y was performed by leaching the protonated zeolite Y (HY) in HCl solution (0.1 and 0.5 M) at 70 °C for 3 h resulting in DY0.1 and DY0.5. Subsequently, HY, DY0.1, and DY0.5 zeolites were immersed in...
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Department of Chemistry, Universitas Gadjah Mada
2020
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oai:doaj.org-article:6a0a28bbec1a4e9bb9396b6366a492302021-12-02T18:41:51ZHydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil1411-94202460-157810.22146/ijc.55645https://doaj.org/article/6a0a28bbec1a4e9bb9396b6366a492302020-11-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/55645https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578The zeolite Y had been successfully modified by HCl and/or NaOH treatment. The modification of zeolite Y was performed by leaching the protonated zeolite Y (HY) in HCl solution (0.1 and 0.5 M) at 70 °C for 3 h resulting in DY0.1 and DY0.5. Subsequently, HY, DY0.1, and DY0.5 zeolites were immersed in 0.1 M NaOH for 15 min at room temperature resulting in AHY, ADY0.1, and ADY0.5. All samples were analyzed for acidity, crystallinity, Si/Al ratio, morphology, and textural properties. The catalytic performance of all samples was investigated in hydrotreating of α-cellulose bio-oil with a catalyst/feed weight ratio of 1/30. The HCl and NaOH treatment led to the decrease of the zeolite Y crystallinity and the increase of the zeolite Y average pore diameter (i.e., the mesopore distribution). The ADY0.5 gave the highest mesopore distribution, which was 43.7%, with an average pore diameter of 4.59 nm. Moreover, both of the treatments were found to increase the Si/Al ratio that caused the decrease of zeolites Y acidity. All the zeolite Y samples gave better catalytic activity to produce liquid products after being treated by NaOH. The sample ADY0.5 managed to produce 6.12% of 1-isopropyl-2,4-dimethylbenzene that has good potential to be processed into fuel.Jason MandelaWega TrisunaryantiTriyono TriyonoMamoru KoketsuDyah Ayu FatmawatiDepartment of Chemistry, Universitas Gadjah Madaarticlehcl treatmentmesoporous structurenaoh treatmentpyrolyzed α-cellulose hydrotreatmentChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 4, Pp 787-796 (2020) |
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hcl treatment mesoporous structure naoh treatment pyrolyzed α-cellulose hydrotreatment Chemistry QD1-999 |
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hcl treatment mesoporous structure naoh treatment pyrolyzed α-cellulose hydrotreatment Chemistry QD1-999 Jason Mandela Wega Trisunaryanti Triyono Triyono Mamoru Koketsu Dyah Ayu Fatmawati Hydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil |
description |
The zeolite Y had been successfully modified by HCl and/or NaOH treatment. The modification of zeolite Y was performed by leaching the protonated zeolite Y (HY) in HCl solution (0.1 and 0.5 M) at 70 °C for 3 h resulting in DY0.1 and DY0.5. Subsequently, HY, DY0.1, and DY0.5 zeolites were immersed in 0.1 M NaOH for 15 min at room temperature resulting in AHY, ADY0.1, and ADY0.5. All samples were analyzed for acidity, crystallinity, Si/Al ratio, morphology, and textural properties. The catalytic performance of all samples was investigated in hydrotreating of α-cellulose bio-oil with a catalyst/feed weight ratio of 1/30. The HCl and NaOH treatment led to the decrease of the zeolite Y crystallinity and the increase of the zeolite Y average pore diameter (i.e., the mesopore distribution). The ADY0.5 gave the highest mesopore distribution, which was 43.7%, with an average pore diameter of 4.59 nm. Moreover, both of the treatments were found to increase the Si/Al ratio that caused the decrease of zeolites Y acidity. All the zeolite Y samples gave better catalytic activity to produce liquid products after being treated by NaOH. The sample ADY0.5 managed to produce 6.12% of 1-isopropyl-2,4-dimethylbenzene that has good potential to be processed into fuel. |
format |
article |
author |
Jason Mandela Wega Trisunaryanti Triyono Triyono Mamoru Koketsu Dyah Ayu Fatmawati |
author_facet |
Jason Mandela Wega Trisunaryanti Triyono Triyono Mamoru Koketsu Dyah Ayu Fatmawati |
author_sort |
Jason Mandela |
title |
Hydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil |
title_short |
Hydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil |
title_full |
Hydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil |
title_fullStr |
Hydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil |
title_full_unstemmed |
Hydrochloric Acid and/or Sodium Hydroxide-modified Zeolite Y for Catalytic Hydrotreating of α-Cellulose Bio-Oil |
title_sort |
hydrochloric acid and/or sodium hydroxide-modified zeolite y for catalytic hydrotreating of α-cellulose bio-oil |
publisher |
Department of Chemistry, Universitas Gadjah Mada |
publishDate |
2020 |
url |
https://doaj.org/article/6a0a28bbec1a4e9bb9396b6366a49230 |
work_keys_str_mv |
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_version_ |
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