Dynamic multiphase semi-crystalline polymers based on thermally reversible pyrazole-urea bonds

Dynamic polymer materials with reversible covalent bonds can reorganize their macromolecular architectures, and thus produce a macroscopic response to the environment. Here, the authors show dynamic covalent polyureas formed by a polyaddition reaction between pyrazoles and diisocyanates at ambient t...

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Autores principales: Wen-Xing Liu, Zhusheng Yang, Zhi Qiao, Long Zhang, Ning Zhao, Sanzhong Luo, Jian Xu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/6accfedf19264acca638e1bf0889b4d8
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Sumario:Dynamic polymer materials with reversible covalent bonds can reorganize their macromolecular architectures, and thus produce a macroscopic response to the environment. Here, the authors show dynamic covalent polyureas formed by a polyaddition reaction between pyrazoles and diisocyanates at ambient temperature in the absence of a catalyst.