The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
The influence of alumina (Al2O3) content and diameter on the viscosity characteristics of the alumina/linear low-density polyethylene (Al2O3/LLDPE) composites was discussed. The composites were fabricated by melt mixing with the two-rotor continuous mixer. The equivalent surface average particle dia...
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2021
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oai:doaj.org-article:6ad38ecf70b54b7c9713440b077c109d2021-12-05T14:10:48ZThe optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter1618-722910.1515/epoly-2021-0077https://doaj.org/article/6ad38ecf70b54b7c9713440b077c109d2021-10-01T00:00:00Zhttps://doi.org/10.1515/epoly-2021-0077https://doaj.org/toc/1618-7229The influence of alumina (Al2O3) content and diameter on the viscosity characteristics of the alumina/linear low-density polyethylene (Al2O3/LLDPE) composites was discussed. The composites were fabricated by melt mixing with the two-rotor continuous mixer. The equivalent surface average particle diameter (d¯A{\bar{d}}_{\text{A}}) of Al2O3 was calculated by the scanning electron microscopic (SEM) images of samples. The steady-state and dynamic rheological measurements were used to study the evolution of viscosity parameters. With the Carreau model fitting to the steady-rate rheological data, zero-shear viscosity η 0, time constant λ, and power law index n of composites were obtained. On this basis, an optimized Carreau model was established by studying the changes of these parameter values. The rheological result presented that the parameter values (η 0, λ, and n) were linearly proportional to the filling content of Al2O3 particles for nano-Al2O3/LLDPE composites. However, these parameters were, respectively, related to d¯A{\bar{d}}_{\text{A}}, d¯A2{\bar{d}}_{\text{A}}^{2}, and d¯A3{\bar{d}}_{\text{A}}^{3} for micron-Al2O3/LLDPE composites.Li GuoZhang MitaoJi HuajianMa YuluChen TaoXie LinshengDe Gruyterarticlerheologycarreau modelal2o3 particle diameteral2o3/lldpe compositesPolymers and polymer manufactureTP1080-1185ENe-Polymers, Vol 21, Iss 1, Pp 742-753 (2021) |
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rheology carreau model al2o3 particle diameter al2o3/lldpe composites Polymers and polymer manufacture TP1080-1185 |
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rheology carreau model al2o3 particle diameter al2o3/lldpe composites Polymers and polymer manufacture TP1080-1185 Li Guo Zhang Mitao Ji Huajian Ma Yulu Chen Tao Xie Linsheng The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter |
description |
The influence of alumina (Al2O3) content and diameter on the viscosity characteristics of the alumina/linear low-density polyethylene (Al2O3/LLDPE) composites was discussed. The composites were fabricated by melt mixing with the two-rotor continuous mixer. The equivalent surface average particle diameter (d¯A{\bar{d}}_{\text{A}}) of Al2O3 was calculated by the scanning electron microscopic (SEM) images of samples. The steady-state and dynamic rheological measurements were used to study the evolution of viscosity parameters. With the Carreau model fitting to the steady-rate rheological data, zero-shear viscosity η
0, time constant λ, and power law index n of composites were obtained. On this basis, an optimized Carreau model was established by studying the changes of these parameter values. The rheological result presented that the parameter values (η
0, λ, and n) were linearly proportional to the filling content of Al2O3 particles for nano-Al2O3/LLDPE composites. However, these parameters were, respectively, related to d¯A{\bar{d}}_{\text{A}}, d¯A2{\bar{d}}_{\text{A}}^{2}, and d¯A3{\bar{d}}_{\text{A}}^{3} for micron-Al2O3/LLDPE composites. |
format |
article |
author |
Li Guo Zhang Mitao Ji Huajian Ma Yulu Chen Tao Xie Linsheng |
author_facet |
Li Guo Zhang Mitao Ji Huajian Ma Yulu Chen Tao Xie Linsheng |
author_sort |
Li Guo |
title |
The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter |
title_short |
The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter |
title_full |
The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter |
title_fullStr |
The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter |
title_full_unstemmed |
The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter |
title_sort |
optimization of carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter |
publisher |
De Gruyter |
publishDate |
2021 |
url |
https://doaj.org/article/6ad38ecf70b54b7c9713440b077c109d |
work_keys_str_mv |
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