The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter

The influence of alumina (Al2O3) content and diameter on the viscosity characteristics of the alumina/linear low-density polyethylene (Al2O3/LLDPE) composites was discussed. The composites were fabricated by melt mixing with the two-rotor continuous mixer. The equivalent surface average particle dia...

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Autores principales: Li Guo, Zhang Mitao, Ji Huajian, Ma Yulu, Chen Tao, Xie Linsheng
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Lenguaje:EN
Publicado: De Gruyter 2021
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spelling oai:doaj.org-article:6ad38ecf70b54b7c9713440b077c109d2021-12-05T14:10:48ZThe optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter1618-722910.1515/epoly-2021-0077https://doaj.org/article/6ad38ecf70b54b7c9713440b077c109d2021-10-01T00:00:00Zhttps://doi.org/10.1515/epoly-2021-0077https://doaj.org/toc/1618-7229The influence of alumina (Al2O3) content and diameter on the viscosity characteristics of the alumina/linear low-density polyethylene (Al2O3/LLDPE) composites was discussed. The composites were fabricated by melt mixing with the two-rotor continuous mixer. The equivalent surface average particle diameter (d¯A{\bar{d}}_{\text{A}}) of Al2O3 was calculated by the scanning electron microscopic (SEM) images of samples. The steady-state and dynamic rheological measurements were used to study the evolution of viscosity parameters. With the Carreau model fitting to the steady-rate rheological data, zero-shear viscosity η 0, time constant λ, and power law index n of composites were obtained. On this basis, an optimized Carreau model was established by studying the changes of these parameter values. The rheological result presented that the parameter values (η 0, λ, and n) were linearly proportional to the filling content of Al2O3 particles for nano-Al2O3/LLDPE composites. However, these parameters were, respectively, related to d¯A{\bar{d}}_{\text{A}}, d¯A2{\bar{d}}_{\text{A}}^{2}, and d¯A3{\bar{d}}_{\text{A}}^{3} for micron-Al2O3/LLDPE composites.Li GuoZhang MitaoJi HuajianMa YuluChen TaoXie LinshengDe Gruyterarticlerheologycarreau modelal2o3 particle diameteral2o3/lldpe compositesPolymers and polymer manufactureTP1080-1185ENe-Polymers, Vol 21, Iss 1, Pp 742-753 (2021)
institution DOAJ
collection DOAJ
language EN
topic rheology
carreau model
al2o3 particle diameter
al2o3/lldpe composites
Polymers and polymer manufacture
TP1080-1185
spellingShingle rheology
carreau model
al2o3 particle diameter
al2o3/lldpe composites
Polymers and polymer manufacture
TP1080-1185
Li Guo
Zhang Mitao
Ji Huajian
Ma Yulu
Chen Tao
Xie Linsheng
The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
description The influence of alumina (Al2O3) content and diameter on the viscosity characteristics of the alumina/linear low-density polyethylene (Al2O3/LLDPE) composites was discussed. The composites were fabricated by melt mixing with the two-rotor continuous mixer. The equivalent surface average particle diameter (d¯A{\bar{d}}_{\text{A}}) of Al2O3 was calculated by the scanning electron microscopic (SEM) images of samples. The steady-state and dynamic rheological measurements were used to study the evolution of viscosity parameters. With the Carreau model fitting to the steady-rate rheological data, zero-shear viscosity η 0, time constant λ, and power law index n of composites were obtained. On this basis, an optimized Carreau model was established by studying the changes of these parameter values. The rheological result presented that the parameter values (η 0, λ, and n) were linearly proportional to the filling content of Al2O3 particles for nano-Al2O3/LLDPE composites. However, these parameters were, respectively, related to d¯A{\bar{d}}_{\text{A}}, d¯A2{\bar{d}}_{\text{A}}^{2}, and d¯A3{\bar{d}}_{\text{A}}^{3} for micron-Al2O3/LLDPE composites.
format article
author Li Guo
Zhang Mitao
Ji Huajian
Ma Yulu
Chen Tao
Xie Linsheng
author_facet Li Guo
Zhang Mitao
Ji Huajian
Ma Yulu
Chen Tao
Xie Linsheng
author_sort Li Guo
title The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
title_short The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
title_full The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
title_fullStr The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
title_full_unstemmed The optimization of Carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
title_sort optimization of carreau model and rheological behavior of alumina/linear low-density polyethylene composites with different alumina content and diameter
publisher De Gruyter
publishDate 2021
url https://doaj.org/article/6ad38ecf70b54b7c9713440b077c109d
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