Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls

Inverse electron-demand cycloadditions in palladium catalysis are inherently limited by the linear selectivity in the allylic substitution step. To overcome this issue, the authors report a synergetic iridium (branched-selective) and amine catalysis in [4+2] cycloadditions of vinyl aminoalcohols wit...

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Autores principales:	Mao-Mao Zhang, Ya-Ni Wang, Bao-Cheng Wang, Xiao-Wang Chen, Liang-Qiu Lu, Wen-Jing Xiao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6b1fe359aea049698ea081237c61b43d
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spelling	oai:doaj.org-article:6b1fe359aea049698ea081237c61b43d2021-12-02T17:31:37ZSynergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls10.1038/s41467-019-10674-32041-1723https://doaj.org/article/6b1fe359aea049698ea081237c61b43d2019-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10674-3https://doaj.org/toc/2041-1723Inverse electron-demand cycloadditions in palladium catalysis are inherently limited by the linear selectivity in the allylic substitution step. To overcome this issue, the authors report a synergetic iridium (branched-selective) and amine catalysis in [4+2] cycloadditions of vinyl aminoalcohols with carbonyls.Mao-Mao ZhangYa-Ni WangBao-Cheng WangXiao-Wang ChenLiang-Qiu LuWen-Jing XiaoNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Mao-Mao Zhang Ya-Ni Wang Bao-Cheng Wang Xiao-Wang Chen Liang-Qiu Lu Wen-Jing Xiao Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls
description	Inverse electron-demand cycloadditions in palladium catalysis are inherently limited by the linear selectivity in the allylic substitution step. To overcome this issue, the authors report a synergetic iridium (branched-selective) and amine catalysis in [4+2] cycloadditions of vinyl aminoalcohols with carbonyls.
format	article
author	Mao-Mao Zhang Ya-Ni Wang Bao-Cheng Wang Xiao-Wang Chen Liang-Qiu Lu Wen-Jing Xiao
author_facet	Mao-Mao Zhang Ya-Ni Wang Bao-Cheng Wang Xiao-Wang Chen Liang-Qiu Lu Wen-Jing Xiao
author_sort	Mao-Mao Zhang
title	Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls
title_short	Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls
title_full	Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls
title_fullStr	Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls
title_full_unstemmed	Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls
title_sort	synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/6b1fe359aea049698ea081237c61b43d
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_version_	1718380558097055744

Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls

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