Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene migratory insertion-enabled 1,4-palladium shif...

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Autores principales:	Yinghua Yu, Pushkin Chakraborty, Jinshuai Song, Lei Zhu, Chunsen Li, Xueliang Huang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6b8511e8bbe74186abd4470321237241
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id	oai:doaj.org-article:6b8511e8bbe74186abd4470321237241
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spelling	oai:doaj.org-article:6b8511e8bbe74186abd44703212372412021-12-02T15:33:53ZEasy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift10.1038/s41467-019-14101-52041-1723https://doaj.org/article/6b8511e8bbe74186abd44703212372412020-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-14101-5https://doaj.org/toc/2041-1723Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene migratory insertion-enabled 1,4-palladium shift.Yinghua YuPushkin ChakrabortyJinshuai SongLei ZhuChunsen LiXueliang HuangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yinghua Yu Pushkin Chakraborty Jinshuai Song Lei Zhu Chunsen Li Xueliang Huang Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift
description	Transannular construction of medium-sized lactones is entropically unfavoured. Herein, the authors describe a strategy for valuable medium-sized lactone synthesis from available benzaldehydes by selective C-H bond functionalization via palladium carbene migratory insertion-enabled 1,4-palladium shift.
format	article
author	Yinghua Yu Pushkin Chakraborty Jinshuai Song Lei Zhu Chunsen Li Xueliang Huang
author_facet	Yinghua Yu Pushkin Chakraborty Jinshuai Song Lei Zhu Chunsen Li Xueliang Huang
author_sort	Yinghua Yu
title	Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift
title_short	Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift
title_full	Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift
title_fullStr	Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift
title_full_unstemmed	Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift
title_sort	easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/6b8511e8bbe74186abd4470321237241
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Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

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