The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses

Experimental results on some physical and optical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx (x = 0÷10 at %) glasses and amorphous films (d~2.0 µm) are presented. The bulk chalcogenide glasses are studied by X-ray diffraction spectroscopy and nanoindentation methods. It is established that...

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Autores principales:	Iaseniuc, Oxana, Harea, Diana, Harea, Evghenii, Volodina, Galina, Iovu, Mihail
Formato:	article
Lenguaje:	EN
Publicado:	D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2013
Materias:	Physics QC1-999 Electronics TK7800-8360
Acceso en línea:	https://doaj.org/article/6bb990282eb54ae0aaa975580cdee43b
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spelling	oai:doaj.org-article:6bb990282eb54ae0aaa975580cdee43b2021-11-21T11:59:44ZThe physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses2537-63651810-648Xhttps://doaj.org/article/6bb990282eb54ae0aaa975580cdee43b2013-06-01T00:00:00Zhttps://mjps.nanotech.md/archive/2013/article/29782https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365Experimental results on some physical and optical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx (x = 0÷10 at %) glasses and amorphous films (d~2.0 µm) are presented. The bulk chalcogenide glasses are studied by X-ray diffraction spectroscopy and nanoindentation methods. It is established that the addition of these amounts of tin (x = 0÷10 at %) does not lead to significant changes in the physical properties of the glass, such as values of stress and Young’s modulus related to the modification of the density and compactness. The XRD measurements show that the Sn impurities in the (As4S3Se3)1-x:Snx do not significantly change the shape of the first sharp diffraction peak (FSDP) of the X-ray diffraction patterns either; the intensity and the position of the FSDP nonmonotonically depend on the Sn concentration. It has been found that the addition of these amounts of tin in (As4S3Se3)1-x:Snx does not lead to significant changes in the glass physical properties, such as values of stress and Young’s modulus related to the modification of the density and compactness. The study of the photoplastic effect is performed in situ, with illumination of the bulk and thin film samples during indentation as well as their indentation after illumination with a green laser (λ = 532 nm) at a power of P = 50 mV/cm2. The hardness is calculated from load-displacement curves by the Oliver-Pharr method. A sharp increase in hardness is registered if the tin concentration exceeds a value of 34% Sn. The hardness H of (As2Se3)1-x:Snx films varies between 115 and 130 kg/mm2. It is found that the hardness H of amorphous thin films is generally higher than the hardness of bulk samples with the same chemical composition. In this study, we are focused on the mechanical characteristics of high-purity As2Se3:Snx thin films.Iaseniuc, OxanaHarea, DianaHarea, EvgheniiVolodina, GalinaIovu, MihailD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 12, Iss 3-4, Pp 181-191 (2013)
institution	DOAJ
collection	DOAJ
language	EN
topic	Physics QC1-999 Electronics TK7800-8360
spellingShingle	Physics QC1-999 Electronics TK7800-8360 Iaseniuc, Oxana Harea, Diana Harea, Evghenii Volodina, Galina Iovu, Mihail The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses
description	Experimental results on some physical and optical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx (x = 0÷10 at %) glasses and amorphous films (d~2.0 µm) are presented. The bulk chalcogenide glasses are studied by X-ray diffraction spectroscopy and nanoindentation methods. It is established that the addition of these amounts of tin (x = 0÷10 at %) does not lead to significant changes in the physical properties of the glass, such as values of stress and Young’s modulus related to the modification of the density and compactness. The XRD measurements show that the Sn impurities in the (As4S3Se3)1-x:Snx do not significantly change the shape of the first sharp diffraction peak (FSDP) of the X-ray diffraction patterns either; the intensity and the position of the FSDP nonmonotonically depend on the Sn concentration. It has been found that the addition of these amounts of tin in (As4S3Se3)1-x:Snx does not lead to significant changes in the glass physical properties, such as values of stress and Young’s modulus related to the modification of the density and compactness. The study of the photoplastic effect is performed in situ, with illumination of the bulk and thin film samples during indentation as well as their indentation after illumination with a green laser (λ = 532 nm) at a power of P = 50 mV/cm2. The hardness is calculated from load-displacement curves by the Oliver-Pharr method. A sharp increase in hardness is registered if the tin concentration exceeds a value of 34% Sn. The hardness H of (As2Se3)1-x:Snx films varies between 115 and 130 kg/mm2. It is found that the hardness H of amorphous thin films is generally higher than the hardness of bulk samples with the same chemical composition. In this study, we are focused on the mechanical characteristics of high-purity As2Se3:Snx thin films.
format	article
author	Iaseniuc, Oxana Harea, Diana Harea, Evghenii Volodina, Galina Iovu, Mihail
author_facet	Iaseniuc, Oxana Harea, Diana Harea, Evghenii Volodina, Galina Iovu, Mihail
author_sort	Iaseniuc, Oxana
title	The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses
title_short	The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses
title_full	The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses
title_fullStr	The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses
title_full_unstemmed	The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses
title_sort	physical properties of (as2se3)1-x:snx and (as4s3se3)1-x:snx glasses
publisher	D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate	2013
url	https://doaj.org/article/6bb990282eb54ae0aaa975580cdee43b
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The physical properties of (As2Se3)1-x:Snx and (As4S3Se3)1-x:Snx glasses

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