Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides

Homoenolates and their higher homologs have much potential, albeit largely unrealized, in transition metal catalysis. Here, the authors report the nickel-catalyzed generation of homoenolates, and their higher homologs, via decarbonylation of cyclic anhydrides, which then undergo cross-coupling with...

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Autores principales:	Tingzhi Lin, Yuanyun Gu, Pengcheng Qian, Haixing Guan, Patrick J. Walsh, Jianyou Mao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6bbdb340e93a49b7b63edeb945bf1fc1
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spelling	oai:doaj.org-article:6bbdb340e93a49b7b63edeb945bf1fc12021-12-02T14:42:15ZNickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides10.1038/s41467-020-19194-x2041-1723https://doaj.org/article/6bbdb340e93a49b7b63edeb945bf1fc12020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19194-xhttps://doaj.org/toc/2041-1723Homoenolates and their higher homologs have much potential, albeit largely unrealized, in transition metal catalysis. Here, the authors report the nickel-catalyzed generation of homoenolates, and their higher homologs, via decarbonylation of cyclic anhydrides, which then undergo cross-coupling with alkyl bromides.Tingzhi LinYuanyun GuPengcheng QianHaixing GuanPatrick J. WalshJianyou MaoNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tingzhi Lin Yuanyun Gu Pengcheng Qian Haixing Guan Patrick J. Walsh Jianyou Mao Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
description	Homoenolates and their higher homologs have much potential, albeit largely unrealized, in transition metal catalysis. Here, the authors report the nickel-catalyzed generation of homoenolates, and their higher homologs, via decarbonylation of cyclic anhydrides, which then undergo cross-coupling with alkyl bromides.
format	article
author	Tingzhi Lin Yuanyun Gu Pengcheng Qian Haixing Guan Patrick J. Walsh Jianyou Mao
author_facet	Tingzhi Lin Yuanyun Gu Pengcheng Qian Haixing Guan Patrick J. Walsh Jianyou Mao
author_sort	Tingzhi Lin
title	Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
title_short	Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
title_full	Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
title_fullStr	Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
title_full_unstemmed	Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
title_sort	nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/6bbdb340e93a49b7b63edeb945bf1fc1
work_keys_str_mv	AT tingzhilin nickelcatalyzedreductivecouplingofhomoenolatesandtheirhigherhomologueswithunactivatedalkylbromides AT yuanyungu nickelcatalyzedreductivecouplingofhomoenolatesandtheirhigherhomologueswithunactivatedalkylbromides AT pengchengqian nickelcatalyzedreductivecouplingofhomoenolatesandtheirhigherhomologueswithunactivatedalkylbromides AT haixingguan nickelcatalyzedreductivecouplingofhomoenolatesandtheirhigherhomologueswithunactivatedalkylbromides AT patrickjwalsh nickelcatalyzedreductivecouplingofhomoenolatesandtheirhigherhomologueswithunactivatedalkylbromides AT jianyoumao nickelcatalyzedreductivecouplingofhomoenolatesandtheirhigherhomologueswithunactivatedalkylbromides
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Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides

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