Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides

Homoenolates and their higher homologs have much potential, albeit largely unrealized, in transition metal catalysis. Here, the authors report the nickel-catalyzed generation of homoenolates, and their higher homologs, via decarbonylation of cyclic anhydrides, which then undergo cross-coupling with...

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Bibliographic Details
Main Authors: Tingzhi Lin, Yuanyun Gu, Pengcheng Qian, Haixing Guan, Patrick J. Walsh, Jianyou Mao
Format: article
Language:EN
Published: Nature Portfolio 2020
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Q
Online Access:https://doaj.org/article/6bbdb340e93a49b7b63edeb945bf1fc1
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