Photocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol
Two series of hybrid inorganic-organic derivatives, obtained via the modification of protonated Ruddlesden–Popper phases H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) with intercalated <i>n</i>-alkylamines and grafte...
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2021
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oai:doaj.org-article:6c213262b39c4d149d0ffa40a636655e2021-11-25T17:05:23ZPhotocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol10.3390/catal111112792073-4344https://doaj.org/article/6c213262b39c4d149d0ffa40a636655e2021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4344/11/11/1279https://doaj.org/toc/2073-4344Two series of hybrid inorganic-organic derivatives, obtained via the modification of protonated Ruddlesden–Popper phases H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) with intercalated <i>n</i>-alkylamines and grafted <i>n</i>-alkoxy groups, have been systematically investigated in relation to photocatalytic hydrogen production from a model of 1 mol % aqueous solution of methanol for the first time. Photocatalytic measurements were performed both for bare samples and for their composites with Pt nanoparticles as a cocatalyst using an advanced scheme, including dark stages, monitoring of the volume concentration of the sample in the reaction suspension during the experiment, shifts of its pH and possible exfoliation of layered compounds into nanolayers. It was found that the incorporation of organic components into the interlayer space of the titanates increases their photocatalytic activity up to 117 times compared with that of the initial compounds. Additional platinization of the hybrid samples’ surface allowed for achieving apparent quantum efficiency of hydrogen evolution of more than 40%. It was established that the photocatalytic activity of the hybrid samples correlates with the hydration degree of their interlayer space, which is considered a separate reaction zone in photocatalysis, and that hydrogen indeed generates from the aqueous methanol solution rather than from organic components of the derivatives.Sergei A. KurnosenkoVladimir V. VoytovichOleg I. SilyukovIvan A. RodionovSergei O. KirichenkoIana A. MinichEkaterina N. MalyginaAlina D. KhramovaIrina A. ZverevaMDPI AGarticlephotocatalysishydrogenlayered perovskitetitanateintercalationgraftingChemical technologyTP1-1185ChemistryQD1-999ENCatalysts, Vol 11, Iss 1279, p 1279 (2021) |
| institution |
DOAJ |
| collection |
DOAJ |
| language |
EN |
| topic |
photocatalysis hydrogen layered perovskite titanate intercalation grafting Chemical technology TP1-1185 Chemistry QD1-999 |
| spellingShingle |
photocatalysis hydrogen layered perovskite titanate intercalation grafting Chemical technology TP1-1185 Chemistry QD1-999 Sergei A. Kurnosenko Vladimir V. Voytovich Oleg I. Silyukov Ivan A. Rodionov Sergei O. Kirichenko Iana A. Minich Ekaterina N. Malygina Alina D. Khramova Irina A. Zvereva Photocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol |
| description |
Two series of hybrid inorganic-organic derivatives, obtained via the modification of protonated Ruddlesden–Popper phases H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) with intercalated <i>n</i>-alkylamines and grafted <i>n</i>-alkoxy groups, have been systematically investigated in relation to photocatalytic hydrogen production from a model of 1 mol % aqueous solution of methanol for the first time. Photocatalytic measurements were performed both for bare samples and for their composites with Pt nanoparticles as a cocatalyst using an advanced scheme, including dark stages, monitoring of the volume concentration of the sample in the reaction suspension during the experiment, shifts of its pH and possible exfoliation of layered compounds into nanolayers. It was found that the incorporation of organic components into the interlayer space of the titanates increases their photocatalytic activity up to 117 times compared with that of the initial compounds. Additional platinization of the hybrid samples’ surface allowed for achieving apparent quantum efficiency of hydrogen evolution of more than 40%. It was established that the photocatalytic activity of the hybrid samples correlates with the hydration degree of their interlayer space, which is considered a separate reaction zone in photocatalysis, and that hydrogen indeed generates from the aqueous methanol solution rather than from organic components of the derivatives. |
| format |
article |
| author |
Sergei A. Kurnosenko Vladimir V. Voytovich Oleg I. Silyukov Ivan A. Rodionov Sergei O. Kirichenko Iana A. Minich Ekaterina N. Malygina Alina D. Khramova Irina A. Zvereva |
| author_facet |
Sergei A. Kurnosenko Vladimir V. Voytovich Oleg I. Silyukov Ivan A. Rodionov Sergei O. Kirichenko Iana A. Minich Ekaterina N. Malygina Alina D. Khramova Irina A. Zvereva |
| author_sort |
Sergei A. Kurnosenko |
| title |
Photocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol |
| title_short |
Photocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol |
| title_full |
Photocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol |
| title_fullStr |
Photocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol |
| title_full_unstemmed |
Photocatalytic Activity of <i>n</i>-Alkylamine and <i>n</i>-Alkoxy Derivatives of Layered Perovskite-like Titanates H<sub>2</sub>Ln<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> (Ln = La, Nd) in the Reaction of Hydrogen Production from an Aqueous Solution of Methanol |
| title_sort |
photocatalytic activity of <i>n</i>-alkylamine and <i>n</i>-alkoxy derivatives of layered perovskite-like titanates h<sub>2</sub>ln<sub>2</sub>ti<sub>3</sub>o<sub>10</sub> (ln = la, nd) in the reaction of hydrogen production from an aqueous solution of methanol |
| publisher |
MDPI AG |
| publishDate |
2021 |
| url |
https://doaj.org/article/6c213262b39c4d149d0ffa40a636655e |
| work_keys_str_mv |
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