Influence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films

The experimental investigation of the influence of the light irradiation and heat treatment on the optical parameters of one of highest sensitive chalcogenide glass As45S15Se40 was investigated. For the amorphous As45S15Se40 thin films prepared by „flash” thermal evaporation, from the transmission s...

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Autores principales: Iovu, Mihail, Benea, Vasile, Colomeico, Eduard, Cojocaru, Ion
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Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2011
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spelling oai:doaj.org-article:6c822a1c3d8442b78c1dfdbab0f9eb652021-11-21T12:01:57ZInfluence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films2537-63651810-648Xhttps://doaj.org/article/6c822a1c3d8442b78c1dfdbab0f9eb652011-08-01T00:00:00Zhttps://mjps.nanotech.md/archive/2011/article/21344https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365The experimental investigation of the influence of the light irradiation and heat treatment on the optical parameters of one of highest sensitive chalcogenide glass As45S15Se40 was investigated. For the amorphous As45S15Se40 thin films prepared by „flash” thermal evaporation, from the transmission spectra the value of the refractive index n was found n = 2.921 at λ = 650 nm, and the optical band gap Eg was determined from the Tauc plot Eg = 1.929 eV. From the dispersion curves of the refractive index n = f(λ) and (n2-1)-1 = f(hv), by fitting a straight line to the experimental points, the single-oscillator energy E0 and the dispersion energy of oscillator strength Ed were estimated. The kinetics of photodarkening in amorphous As45S15Se40 thin films is described by a stretch exponential function, and the effect at illumination with laser beam λ = 540 nm is more pronounced than in amorphous As2S3 and As2Se3 films. The maximum of the diffraction efficiency λ of the holografical gratings recorded during the exposure of laser beam at λ = 540 nm is reached at about t = 250 s.Iovu, MihailBenea, VasileColomeico, EduardCojocaru, IonD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 10, Iss 3-4, Pp 275-283 (2011)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Iovu, Mihail
Benea, Vasile
Colomeico, Eduard
Cojocaru, Ion
Influence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films
description The experimental investigation of the influence of the light irradiation and heat treatment on the optical parameters of one of highest sensitive chalcogenide glass As45S15Se40 was investigated. For the amorphous As45S15Se40 thin films prepared by „flash” thermal evaporation, from the transmission spectra the value of the refractive index n was found n = 2.921 at λ = 650 nm, and the optical band gap Eg was determined from the Tauc plot Eg = 1.929 eV. From the dispersion curves of the refractive index n = f(λ) and (n2-1)-1 = f(hv), by fitting a straight line to the experimental points, the single-oscillator energy E0 and the dispersion energy of oscillator strength Ed were estimated. The kinetics of photodarkening in amorphous As45S15Se40 thin films is described by a stretch exponential function, and the effect at illumination with laser beam λ = 540 nm is more pronounced than in amorphous As2S3 and As2Se3 films. The maximum of the diffraction efficiency λ of the holografical gratings recorded during the exposure of laser beam at λ = 540 nm is reached at about t = 250 s.
format article
author Iovu, Mihail
Benea, Vasile
Colomeico, Eduard
Cojocaru, Ion
author_facet Iovu, Mihail
Benea, Vasile
Colomeico, Eduard
Cojocaru, Ion
author_sort Iovu, Mihail
title Influence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films
title_short Influence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films
title_full Influence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films
title_fullStr Influence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films
title_full_unstemmed Influence of light irradition and heat treatment on the optical properties of amorphous As45S15Se40 thin films
title_sort influence of light irradition and heat treatment on the optical properties of amorphous as45s15se40 thin films
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2011
url https://doaj.org/article/6c822a1c3d8442b78c1dfdbab0f9eb65
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