Site-switchable mono-O-allylation of polyols

Selective manipulation of one functional group, out of many repeatedly occurring in a substrate, represents a grand challenge in chemistry. Here, the authors report a Pd/Lewis acid cocatalytic system that achieves not only site-selective, but also site-switchable mono-O-allylation of polyols.

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Autores principales:	Hua Tang, Yu-Biao Tian, Hongyan Cui, Ren-Zhe Li, Xia Zhang, Dawen Niu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6cf8f138943144b498ec6401106dd12b
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spelling	oai:doaj.org-article:6cf8f138943144b498ec6401106dd12b2021-12-02T17:31:55ZSite-switchable mono-O-allylation of polyols10.1038/s41467-020-19348-x2041-1723https://doaj.org/article/6cf8f138943144b498ec6401106dd12b2020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19348-xhttps://doaj.org/toc/2041-1723Selective manipulation of one functional group, out of many repeatedly occurring in a substrate, represents a grand challenge in chemistry. Here, the authors report a Pd/Lewis acid cocatalytic system that achieves not only site-selective, but also site-switchable mono-O-allylation of polyols.Hua TangYu-Biao TianHongyan CuiRen-Zhe LiXia ZhangDawen NiuNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Hua Tang Yu-Biao Tian Hongyan Cui Ren-Zhe Li Xia Zhang Dawen Niu Site-switchable mono-O-allylation of polyols
description	Selective manipulation of one functional group, out of many repeatedly occurring in a substrate, represents a grand challenge in chemistry. Here, the authors report a Pd/Lewis acid cocatalytic system that achieves not only site-selective, but also site-switchable mono-O-allylation of polyols.
format	article
author	Hua Tang Yu-Biao Tian Hongyan Cui Ren-Zhe Li Xia Zhang Dawen Niu
author_facet	Hua Tang Yu-Biao Tian Hongyan Cui Ren-Zhe Li Xia Zhang Dawen Niu
author_sort	Hua Tang
title	Site-switchable mono-O-allylation of polyols
title_short	Site-switchable mono-O-allylation of polyols
title_full	Site-switchable mono-O-allylation of polyols
title_fullStr	Site-switchable mono-O-allylation of polyols
title_full_unstemmed	Site-switchable mono-O-allylation of polyols
title_sort	site-switchable mono-o-allylation of polyols
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/6cf8f138943144b498ec6401106dd12b
work_keys_str_mv	AT huatang siteswitchablemonooallylationofpolyols AT yubiaotian siteswitchablemonooallylationofpolyols AT hongyancui siteswitchablemonooallylationofpolyols AT renzheli siteswitchablemonooallylationofpolyols AT xiazhang siteswitchablemonooallylationofpolyols AT dawenniu siteswitchablemonooallylationofpolyols
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Site-switchable mono-O-allylation of polyols

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