Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling

Metallic clusters with an excess electron beyond a closed shell have very low ionization energies, in analogy to alkali atoms. Here, the authors use select ligands to lower the ionization energy of metallic clusters without changing the number of valence electrons, introducing a route to alkali-like...

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Autores principales:	Vikas Chauhan, Arthur C. Reber, Shiv N. Khanna
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6d13e3b85ff24511bbd50ef22b0286c0
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spelling	oai:doaj.org-article:6d13e3b85ff24511bbd50ef22b0286c02021-12-02T16:56:39ZStrong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling10.1038/s41467-018-04799-02041-1723https://doaj.org/article/6d13e3b85ff24511bbd50ef22b0286c02018-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04799-0https://doaj.org/toc/2041-1723Metallic clusters with an excess electron beyond a closed shell have very low ionization energies, in analogy to alkali atoms. Here, the authors use select ligands to lower the ionization energy of metallic clusters without changing the number of valence electrons, introducing a route to alkali-like superatoms that is independent of the final shell occupancy.Vikas ChauhanArthur C. ReberShiv N. KhannaNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Vikas Chauhan Arthur C. Reber Shiv N. Khanna Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
description	Metallic clusters with an excess electron beyond a closed shell have very low ionization energies, in analogy to alkali atoms. Here, the authors use select ligands to lower the ionization energy of metallic clusters without changing the number of valence electrons, introducing a route to alkali-like superatoms that is independent of the final shell occupancy.
format	article
author	Vikas Chauhan Arthur C. Reber Shiv N. Khanna
author_facet	Vikas Chauhan Arthur C. Reber Shiv N. Khanna
author_sort	Vikas Chauhan
title	Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
title_short	Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
title_full	Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
title_fullStr	Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
title_full_unstemmed	Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
title_sort	strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/6d13e3b85ff24511bbd50ef22b0286c0
work_keys_str_mv	AT vikaschauhan strongloweringofionizationenergyofmetallicclustersbyorganicligandswithoutchangingshellfilling AT arthurcreber strongloweringofionizationenergyofmetallicclustersbyorganicligandswithoutchangingshellfilling AT shivnkhanna strongloweringofionizationenergyofmetallicclustersbyorganicligandswithoutchangingshellfilling
_version_	1718382743532863488

Strong lowering of ionization energy of metallic clusters by organic ligands without changing shell filling

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