Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine

Alkenylpyridines are versatile building blocks for the synthesis of drugs and other complex molecular structures. Here, the authors show a branch-selective pyridylation of alkenes via sulfinate-assisted photoredox catalysis and showcase its utility in an expedient synthesis of Triprolidine.

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Autores principales:	Shengqing Zhu, Jian Qin, Fang Wang, Huan Li, Lingling Chu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6d40b876cb7e4c64b129ff5e1e8b18a8
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spelling	oai:doaj.org-article:6d40b876cb7e4c64b129ff5e1e8b18a82021-12-02T14:39:16ZPhotoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine10.1038/s41467-019-08669-12041-1723https://doaj.org/article/6d40b876cb7e4c64b129ff5e1e8b18a82019-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08669-1https://doaj.org/toc/2041-1723Alkenylpyridines are versatile building blocks for the synthesis of drugs and other complex molecular structures. Here, the authors show a branch-selective pyridylation of alkenes via sulfinate-assisted photoredox catalysis and showcase its utility in an expedient synthesis of Triprolidine.Shengqing ZhuJian QinFang WangHuan LiLingling ChuNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shengqing Zhu Jian Qin Fang Wang Huan Li Lingling Chu Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine
description	Alkenylpyridines are versatile building blocks for the synthesis of drugs and other complex molecular structures. Here, the authors show a branch-selective pyridylation of alkenes via sulfinate-assisted photoredox catalysis and showcase its utility in an expedient synthesis of Triprolidine.
format	article
author	Shengqing Zhu Jian Qin Fang Wang Huan Li Lingling Chu
author_facet	Shengqing Zhu Jian Qin Fang Wang Huan Li Lingling Chu
author_sort	Shengqing Zhu
title	Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine
title_short	Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine
title_full	Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine
title_fullStr	Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine
title_full_unstemmed	Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine
title_sort	photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of triprolidine
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/6d40b876cb7e4c64b129ff5e1e8b18a8
work_keys_str_mv	AT shengqingzhu photoredoxcatalyzedbranchselectivepyridylationofalkenesfortheexpedientsynthesisoftriprolidine AT jianqin photoredoxcatalyzedbranchselectivepyridylationofalkenesfortheexpedientsynthesisoftriprolidine AT fangwang photoredoxcatalyzedbranchselectivepyridylationofalkenesfortheexpedientsynthesisoftriprolidine AT huanli photoredoxcatalyzedbranchselectivepyridylationofalkenesfortheexpedientsynthesisoftriprolidine AT linglingchu photoredoxcatalyzedbranchselectivepyridylationofalkenesfortheexpedientsynthesisoftriprolidine
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Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine

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