Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium
Olefin and emulsion polymerizations are incompatible due to the water sensitivity of olefin polymerization catalysts and thus direct synthesis of semi-crystalline polyolefin latexes is difficult. Here, the authors encapsulate a catalyst precursor in micelles which act as nanoreactors for ethylene po...
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Nature Portfolio
2018
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oai:doaj.org-article:6d473082719a4b898d6944db94bc21732021-12-02T16:56:42ZEncapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium10.1038/s41467-018-03253-52041-1723https://doaj.org/article/6d473082719a4b898d6944db94bc21732018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-03253-5https://doaj.org/toc/2041-1723Olefin and emulsion polymerizations are incompatible due to the water sensitivity of olefin polymerization catalysts and thus direct synthesis of semi-crystalline polyolefin latexes is difficult. Here, the authors encapsulate a catalyst precursor in micelles which act as nanoreactors for ethylene polymerization in water.Camille Boucher-JacobsMuhammad RabnawazJoshua S. KatzRalph EvenDamien GuironnetNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018) |
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Science Q Camille Boucher-Jacobs Muhammad Rabnawaz Joshua S. Katz Ralph Even Damien Guironnet Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium |
description |
Olefin and emulsion polymerizations are incompatible due to the water sensitivity of olefin polymerization catalysts and thus direct synthesis of semi-crystalline polyolefin latexes is difficult. Here, the authors encapsulate a catalyst precursor in micelles which act as nanoreactors for ethylene polymerization in water. |
format |
article |
author |
Camille Boucher-Jacobs Muhammad Rabnawaz Joshua S. Katz Ralph Even Damien Guironnet |
author_facet |
Camille Boucher-Jacobs Muhammad Rabnawaz Joshua S. Katz Ralph Even Damien Guironnet |
author_sort |
Camille Boucher-Jacobs |
title |
Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium |
title_short |
Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium |
title_full |
Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium |
title_fullStr |
Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium |
title_full_unstemmed |
Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium |
title_sort |
encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/6d473082719a4b898d6944db94bc2173 |
work_keys_str_mv |
AT camilleboucherjacobs encapsulationofcatalystinblockcopolymermicellesforthepolymerizationofethyleneinaqueousmedium AT muhammadrabnawaz encapsulationofcatalystinblockcopolymermicellesforthepolymerizationofethyleneinaqueousmedium AT joshuaskatz encapsulationofcatalystinblockcopolymermicellesforthepolymerizationofethyleneinaqueousmedium AT ralpheven encapsulationofcatalystinblockcopolymermicellesforthepolymerizationofethyleneinaqueousmedium AT damienguironnet encapsulationofcatalystinblockcopolymermicellesforthepolymerizationofethyleneinaqueousmedium |
_version_ |
1718382743947051008 |