Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings

Owing to the propensity for uranium(III) compounds to undergo disproportionation, uranium-element multiple bonds involving uranium(III) oxidation states remain rare. Here the authors report hexauranium-methanediide rings that formally contain uranium(III)- and uranium(IV)-methanediides supported by...

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Autores principales:	Ashley J. Wooles, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Gareth T. W. Law, Adam J. Fuller, Felipe Kremer, Mark Ridgway, William Lewis, Laura Gagliardi, Bess Vlaisavljevich, Stephen T. Liddle
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6d5b982b9054495bbc0c7c6c9cd21250
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spelling	oai:doaj.org-article:6d5b982b9054495bbc0c7c6c9cd212502021-12-02T14:40:08ZUranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings10.1038/s41467-018-04560-72041-1723https://doaj.org/article/6d5b982b9054495bbc0c7c6c9cd212502018-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-04560-7https://doaj.org/toc/2041-1723Owing to the propensity for uranium(III) compounds to undergo disproportionation, uranium-element multiple bonds involving uranium(III) oxidation states remain rare. Here the authors report hexauranium-methanediide rings that formally contain uranium(III)- and uranium(IV)-methanediides supported by alternating halide and arene bridges.Ashley J. WoolesDavid P. MillsFloriana TunaEric J. L. McInnesGareth T. W. LawAdam J. FullerFelipe KremerMark RidgwayWilliam LewisLaura GagliardiBess VlaisavljevichStephen T. LiddleNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-11 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Ashley J. Wooles David P. Mills Floriana Tuna Eric J. L. McInnes Gareth T. W. Law Adam J. Fuller Felipe Kremer Mark Ridgway William Lewis Laura Gagliardi Bess Vlaisavljevich Stephen T. Liddle Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
description	Owing to the propensity for uranium(III) compounds to undergo disproportionation, uranium-element multiple bonds involving uranium(III) oxidation states remain rare. Here the authors report hexauranium-methanediide rings that formally contain uranium(III)- and uranium(IV)-methanediides supported by alternating halide and arene bridges.
format	article
author	Ashley J. Wooles David P. Mills Floriana Tuna Eric J. L. McInnes Gareth T. W. Law Adam J. Fuller Felipe Kremer Mark Ridgway William Lewis Laura Gagliardi Bess Vlaisavljevich Stephen T. Liddle
author_facet	Ashley J. Wooles David P. Mills Floriana Tuna Eric J. L. McInnes Gareth T. W. Law Adam J. Fuller Felipe Kremer Mark Ridgway William Lewis Laura Gagliardi Bess Vlaisavljevich Stephen T. Liddle
author_sort	Ashley J. Wooles
title	Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
title_short	Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
title_full	Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
title_fullStr	Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
title_full_unstemmed	Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
title_sort	uranium(iii)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/6d5b982b9054495bbc0c7c6c9cd21250
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Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings

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