A Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries
Solid-state batteries (SSBs) have attracted considerable attention for high-energy-density and high-safety energy storage devices. Many efforts have focused on the thin solid-state-electrolyte (SSE) films with high room-temperature ionic conductivity, flexibility, and mechanical strength. Here, we r...
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MDPI AG
2021
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oai:doaj.org-article:6dba06f37e0f4a0c81d3fd7bb532fc9a2021-11-11T18:41:42ZA Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries10.3390/polym132136222073-4360https://doaj.org/article/6dba06f37e0f4a0c81d3fd7bb532fc9a2021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/21/3622https://doaj.org/toc/2073-4360Solid-state batteries (SSBs) have attracted considerable attention for high-energy-density and high-safety energy storage devices. Many efforts have focused on the thin solid-state-electrolyte (SSE) films with high room-temperature ionic conductivity, flexibility, and mechanical strength. Here, we report a composite polymer electrolyte (CPE) reinforced by electrospun PI nanofiber film, combining with succinonitrile-based solid composite electrolyte. In situ photo-polymerization method is used for the preparation of the CPE. This CPE, with a thickness around 32.5 μm, shows a high ionic conductivity of 2.64 × 10<sup>−4</sup> S cm<sup>−</sup><sup>1</sup> at room temperature. It is also fireproof and mechanically strong, showing great promise for an SSB device with high energy density and high safety.Boheng YuanBin ZhaoZhi CongZhi ChengQi WangYafei LuXiaogang HanMDPI AGarticleelectrospinningpolyimidesolid state batteriescomposite polymer electrolytephoto polymerizationfireproofOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3622, p 3622 (2021) |
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electrospinning polyimide solid state batteries composite polymer electrolyte photo polymerization fireproof Organic chemistry QD241-441 |
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electrospinning polyimide solid state batteries composite polymer electrolyte photo polymerization fireproof Organic chemistry QD241-441 Boheng Yuan Bin Zhao Zhi Cong Zhi Cheng Qi Wang Yafei Lu Xiaogang Han A Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries |
description |
Solid-state batteries (SSBs) have attracted considerable attention for high-energy-density and high-safety energy storage devices. Many efforts have focused on the thin solid-state-electrolyte (SSE) films with high room-temperature ionic conductivity, flexibility, and mechanical strength. Here, we report a composite polymer electrolyte (CPE) reinforced by electrospun PI nanofiber film, combining with succinonitrile-based solid composite electrolyte. In situ photo-polymerization method is used for the preparation of the CPE. This CPE, with a thickness around 32.5 μm, shows a high ionic conductivity of 2.64 × 10<sup>−4</sup> S cm<sup>−</sup><sup>1</sup> at room temperature. It is also fireproof and mechanically strong, showing great promise for an SSB device with high energy density and high safety. |
format |
article |
author |
Boheng Yuan Bin Zhao Zhi Cong Zhi Cheng Qi Wang Yafei Lu Xiaogang Han |
author_facet |
Boheng Yuan Bin Zhao Zhi Cong Zhi Cheng Qi Wang Yafei Lu Xiaogang Han |
author_sort |
Boheng Yuan |
title |
A Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries |
title_short |
A Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries |
title_full |
A Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries |
title_fullStr |
A Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries |
title_full_unstemmed |
A Flexible, Fireproof, Composite Polymer Electrolyte Reinforced by Electrospun Polyimide for Room-Temperature Solid-State Batteries |
title_sort |
flexible, fireproof, composite polymer electrolyte reinforced by electrospun polyimide for room-temperature solid-state batteries |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/6dba06f37e0f4a0c81d3fd7bb532fc9a |
work_keys_str_mv |
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