A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices

Optical chemosensors with surface plasmon resonance (SPR) transduction are widely employed, even in complex environments, such as those outside the laboratory. In this context, not only the chemical nature but also the physical form of the receptor layer is particularly relevant. Synthetic receptors...

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Autores principales: Maria Pesavento, Nunzio Cennamo, Luigi Zeni, Letizia De Maria
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/6dfb55cfe4e945e1b7adb7d2ed45a718
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spelling oai:doaj.org-article:6dfb55cfe4e945e1b7adb7d2ed45a7182021-11-11T15:23:56ZA Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices10.3390/app1121103902076-3417https://doaj.org/article/6dfb55cfe4e945e1b7adb7d2ed45a7182021-11-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/21/10390https://doaj.org/toc/2076-3417Optical chemosensors with surface plasmon resonance (SPR) transduction are widely employed, even in complex environments, such as those outside the laboratory. In this context, not only the chemical nature but also the physical form of the receptor layer is particularly relevant. Synthetic receptors as molecularly imprinted polymers (MIPs) are well suited. This is demonstrated here in the case of an SPR sensor platform based on a multimode plastic optical fiber, which is very promising for on site application due to the low dimensions and low cost. A specific MIP was used as the receptor, with high affinity for the substance to be determined, 2-furaldehyde, in water. Here, a medium of high refractive index, i.e., vegetable oil, was considered because of the high interest for its determination in industrial diagnostics. The effects of the MIP layer thickness and the washing extent on the quality of the analytical signal were investigated. Better spectra were generated at the thinner MIP layer, while a lower detection limit is reached with extended washing.Maria PesaventoNunzio CennamoLuigi ZeniLetizia De MariaMDPI AGarticlemolecularly imprinted polymeroptical sensorplastic optical fibersurface plasmon resonance2-furaldehydevegetable oilTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 10390, p 10390 (2021)
institution DOAJ
collection DOAJ
language EN
topic molecularly imprinted polymer
optical sensor
plastic optical fiber
surface plasmon resonance
2-furaldehyde
vegetable oil
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
spellingShingle molecularly imprinted polymer
optical sensor
plastic optical fiber
surface plasmon resonance
2-furaldehyde
vegetable oil
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
Maria Pesavento
Nunzio Cennamo
Luigi Zeni
Letizia De Maria
A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices
description Optical chemosensors with surface plasmon resonance (SPR) transduction are widely employed, even in complex environments, such as those outside the laboratory. In this context, not only the chemical nature but also the physical form of the receptor layer is particularly relevant. Synthetic receptors as molecularly imprinted polymers (MIPs) are well suited. This is demonstrated here in the case of an SPR sensor platform based on a multimode plastic optical fiber, which is very promising for on site application due to the low dimensions and low cost. A specific MIP was used as the receptor, with high affinity for the substance to be determined, 2-furaldehyde, in water. Here, a medium of high refractive index, i.e., vegetable oil, was considered because of the high interest for its determination in industrial diagnostics. The effects of the MIP layer thickness and the washing extent on the quality of the analytical signal were investigated. Better spectra were generated at the thinner MIP layer, while a lower detection limit is reached with extended washing.
format article
author Maria Pesavento
Nunzio Cennamo
Luigi Zeni
Letizia De Maria
author_facet Maria Pesavento
Nunzio Cennamo
Luigi Zeni
Letizia De Maria
author_sort Maria Pesavento
title A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices
title_short A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices
title_full A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices
title_fullStr A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices
title_full_unstemmed A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices
title_sort molecularly imprinted polymer based spr sensor for 2-furaldehyde determination in oil matrices
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/6dfb55cfe4e945e1b7adb7d2ed45a718
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