A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices
Optical chemosensors with surface plasmon resonance (SPR) transduction are widely employed, even in complex environments, such as those outside the laboratory. In this context, not only the chemical nature but also the physical form of the receptor layer is particularly relevant. Synthetic receptors...
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oai:doaj.org-article:6dfb55cfe4e945e1b7adb7d2ed45a7182021-11-11T15:23:56ZA Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices10.3390/app1121103902076-3417https://doaj.org/article/6dfb55cfe4e945e1b7adb7d2ed45a7182021-11-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/21/10390https://doaj.org/toc/2076-3417Optical chemosensors with surface plasmon resonance (SPR) transduction are widely employed, even in complex environments, such as those outside the laboratory. In this context, not only the chemical nature but also the physical form of the receptor layer is particularly relevant. Synthetic receptors as molecularly imprinted polymers (MIPs) are well suited. This is demonstrated here in the case of an SPR sensor platform based on a multimode plastic optical fiber, which is very promising for on site application due to the low dimensions and low cost. A specific MIP was used as the receptor, with high affinity for the substance to be determined, 2-furaldehyde, in water. Here, a medium of high refractive index, i.e., vegetable oil, was considered because of the high interest for its determination in industrial diagnostics. The effects of the MIP layer thickness and the washing extent on the quality of the analytical signal were investigated. Better spectra were generated at the thinner MIP layer, while a lower detection limit is reached with extended washing.Maria PesaventoNunzio CennamoLuigi ZeniLetizia De MariaMDPI AGarticlemolecularly imprinted polymeroptical sensorplastic optical fibersurface plasmon resonance2-furaldehydevegetable oilTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 10390, p 10390 (2021) |
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topic |
molecularly imprinted polymer optical sensor plastic optical fiber surface plasmon resonance 2-furaldehyde vegetable oil Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 |
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molecularly imprinted polymer optical sensor plastic optical fiber surface plasmon resonance 2-furaldehyde vegetable oil Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 Maria Pesavento Nunzio Cennamo Luigi Zeni Letizia De Maria A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices |
description |
Optical chemosensors with surface plasmon resonance (SPR) transduction are widely employed, even in complex environments, such as those outside the laboratory. In this context, not only the chemical nature but also the physical form of the receptor layer is particularly relevant. Synthetic receptors as molecularly imprinted polymers (MIPs) are well suited. This is demonstrated here in the case of an SPR sensor platform based on a multimode plastic optical fiber, which is very promising for on site application due to the low dimensions and low cost. A specific MIP was used as the receptor, with high affinity for the substance to be determined, 2-furaldehyde, in water. Here, a medium of high refractive index, i.e., vegetable oil, was considered because of the high interest for its determination in industrial diagnostics. The effects of the MIP layer thickness and the washing extent on the quality of the analytical signal were investigated. Better spectra were generated at the thinner MIP layer, while a lower detection limit is reached with extended washing. |
format |
article |
author |
Maria Pesavento Nunzio Cennamo Luigi Zeni Letizia De Maria |
author_facet |
Maria Pesavento Nunzio Cennamo Luigi Zeni Letizia De Maria |
author_sort |
Maria Pesavento |
title |
A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices |
title_short |
A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices |
title_full |
A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices |
title_fullStr |
A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices |
title_full_unstemmed |
A Molecularly Imprinted Polymer Based SPR Sensor for 2-Furaldehyde Determination in Oil Matrices |
title_sort |
molecularly imprinted polymer based spr sensor for 2-furaldehyde determination in oil matrices |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/6dfb55cfe4e945e1b7adb7d2ed45a718 |
work_keys_str_mv |
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