Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water
Construction and demolition waste from the whole planet is around 3 billion tons per year. Steel-based waste is one of the most significant which was estimated at about 10% of total construction waste. In this study, a catalyst derived from rebar flakes waste (RFW) was investigated for heterogeneous...
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Tamkang University Press
2021
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oai:doaj.org-article:6e72de44f16641998f2685ea0f46edea2021-11-24T14:01:00ZHeterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water10.6180/jase.202206_25(3).00032708-99672708-9975https://doaj.org/article/6e72de44f16641998f2685ea0f46edea2021-11-01T00:00:00Zhttp://jase.tku.edu.tw/articles/jase-202206-25-3-0003https://doaj.org/toc/2708-9967https://doaj.org/toc/2708-9975Construction and demolition waste from the whole planet is around 3 billion tons per year. Steel-based waste is one of the most significant which was estimated at about 10% of total construction waste. In this study, a catalyst derived from rebar flakes waste (RFW) was investigated for heterogeneous Fenton oxidation of methyl orange (MO) in water. The catalyst was characterized using Particle Size Analyzer, SEM-EDX analysis, XRD analysis, and AAS analysis. RFW catalyst contains 60.19% (in wt) of iron, in form of magnetite (Fe3O4), hematite (Fe2O3), and wustite (FeO). RFW catalyse Fenton oxidation of MO was investigated under various experimental conditions as follows: catalyst dosage (0.5-1.5 g/L), oxidant dosage (3.3-26.4 mM), pollutant concentration (10-200 ppm), pH (2-4), and temperature (30-60◦C). Decolourisation of MO was improved by high catalyst dosage, acidic solution, and high temperature. Decolourisation up to 97% in 3 hours was observed at 0.75 g/L RFW catalyst, 6.6 mM H2O2, solution pH at 3, and temperature at 60◦C. Evaluation of iron leaching suggests that the Fenton oxidation of MO was due to the concomitant reaction of the heterogeneous and homogeneous pathway. Sandyanto AdityosulindroAmadira RahdhaniDjoko M. HartonoTamkang University Pressarticlefenton catalystconstruction wasteadvanced oxidation processesdye removaloperating parametersEngineering (General). Civil engineering (General)TA1-2040Chemical engineeringTP155-156PhysicsQC1-999ENJournal of Applied Science and Engineering, Vol 25, Iss 3, Pp 381-388 (2021) |
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fenton catalyst construction waste advanced oxidation processes dye removal operating parameters Engineering (General). Civil engineering (General) TA1-2040 Chemical engineering TP155-156 Physics QC1-999 |
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fenton catalyst construction waste advanced oxidation processes dye removal operating parameters Engineering (General). Civil engineering (General) TA1-2040 Chemical engineering TP155-156 Physics QC1-999 Sandyanto Adityosulindro Amadira Rahdhani Djoko M. Hartono Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water |
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Construction and demolition waste from the whole planet is around 3 billion tons per year. Steel-based waste is one of the most significant which was estimated at about 10% of total construction waste. In this study, a catalyst derived from rebar flakes waste (RFW) was investigated for heterogeneous Fenton oxidation of methyl orange (MO) in water. The catalyst was characterized using Particle Size Analyzer, SEM-EDX analysis, XRD analysis, and AAS analysis. RFW catalyst contains 60.19% (in wt) of iron, in form of magnetite (Fe3O4), hematite (Fe2O3), and wustite (FeO). RFW catalyse Fenton oxidation of MO was investigated under various experimental conditions as follows: catalyst dosage (0.5-1.5 g/L), oxidant dosage (3.3-26.4 mM), pollutant concentration (10-200 ppm), pH (2-4), and temperature (30-60◦C). Decolourisation of MO was improved by high catalyst dosage, acidic solution, and high temperature. Decolourisation up to 97% in 3 hours was observed at 0.75 g/L RFW catalyst, 6.6 mM H2O2, solution pH at 3, and temperature at 60◦C. Evaluation of iron leaching suggests that the Fenton oxidation of MO was due to the concomitant reaction of the heterogeneous and homogeneous pathway. |
format |
article |
author |
Sandyanto Adityosulindro Amadira Rahdhani Djoko M. Hartono |
author_facet |
Sandyanto Adityosulindro Amadira Rahdhani Djoko M. Hartono |
author_sort |
Sandyanto Adityosulindro |
title |
Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water |
title_short |
Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water |
title_full |
Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water |
title_fullStr |
Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water |
title_full_unstemmed |
Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water |
title_sort |
heterogeneous fenton oxidation catalysed by rebar flakes waste for removal of methyl orange in water |
publisher |
Tamkang University Press |
publishDate |
2021 |
url |
https://doaj.org/article/6e72de44f16641998f2685ea0f46edea |
work_keys_str_mv |
AT sandyantoadityosulindro heterogeneousfentonoxidationcatalysedbyrebarflakeswasteforremovalofmethylorangeinwater AT amadirarahdhani heterogeneousfentonoxidationcatalysedbyrebarflakeswasteforremovalofmethylorangeinwater AT djokomhartono heterogeneousfentonoxidationcatalysedbyrebarflakeswasteforremovalofmethylorangeinwater |
_version_ |
1718415054189101056 |