Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water

Construction and demolition waste from the whole planet is around 3 billion tons per year. Steel-based waste is one of the most significant which was estimated at about 10% of total construction waste. In this study, a catalyst derived from rebar flakes waste (RFW) was investigated for heterogeneous...

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Autores principales: Sandyanto Adityosulindro, Amadira Rahdhani, Djoko M. Hartono
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Publicado: Tamkang University Press 2021
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Acceso en línea:https://doaj.org/article/6e72de44f16641998f2685ea0f46edea
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spelling oai:doaj.org-article:6e72de44f16641998f2685ea0f46edea2021-11-24T14:01:00ZHeterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water10.6180/jase.202206_25(3).00032708-99672708-9975https://doaj.org/article/6e72de44f16641998f2685ea0f46edea2021-11-01T00:00:00Zhttp://jase.tku.edu.tw/articles/jase-202206-25-3-0003https://doaj.org/toc/2708-9967https://doaj.org/toc/2708-9975Construction and demolition waste from the whole planet is around 3 billion tons per year. Steel-based waste is one of the most significant which was estimated at about 10% of total construction waste. In this study, a catalyst derived from rebar flakes waste (RFW) was investigated for heterogeneous Fenton oxidation of methyl orange (MO) in water. The catalyst was characterized using Particle Size Analyzer, SEM-EDX analysis, XRD analysis, and AAS analysis. RFW catalyst contains 60.19% (in wt) of iron, in form of magnetite (Fe3O4), hematite (Fe2O3), and wustite (FeO). RFW catalyse Fenton oxidation of MO was investigated under various experimental conditions as follows: catalyst dosage (0.5-1.5 g/L), oxidant dosage (3.3-26.4 mM), pollutant concentration (10-200 ppm), pH (2-4), and temperature (30-60◦C). Decolourisation of MO was improved by high catalyst dosage, acidic solution, and high temperature. Decolourisation up to 97% in 3 hours was observed at 0.75 g/L RFW catalyst, 6.6 mM H2O2, solution pH at 3, and temperature at 60◦C. Evaluation of iron leaching suggests that the Fenton oxidation of MO was due to the concomitant reaction of the heterogeneous and homogeneous pathway. Sandyanto AdityosulindroAmadira RahdhaniDjoko M. HartonoTamkang University Pressarticlefenton catalystconstruction wasteadvanced oxidation processesdye removaloperating parametersEngineering (General). Civil engineering (General)TA1-2040Chemical engineeringTP155-156PhysicsQC1-999ENJournal of Applied Science and Engineering, Vol 25, Iss 3, Pp 381-388 (2021)
institution DOAJ
collection DOAJ
language EN
topic fenton catalyst
construction waste
advanced oxidation processes
dye removal
operating parameters
Engineering (General). Civil engineering (General)
TA1-2040
Chemical engineering
TP155-156
Physics
QC1-999
spellingShingle fenton catalyst
construction waste
advanced oxidation processes
dye removal
operating parameters
Engineering (General). Civil engineering (General)
TA1-2040
Chemical engineering
TP155-156
Physics
QC1-999
Sandyanto Adityosulindro
Amadira Rahdhani
Djoko M. Hartono
Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water
description Construction and demolition waste from the whole planet is around 3 billion tons per year. Steel-based waste is one of the most significant which was estimated at about 10% of total construction waste. In this study, a catalyst derived from rebar flakes waste (RFW) was investigated for heterogeneous Fenton oxidation of methyl orange (MO) in water. The catalyst was characterized using Particle Size Analyzer, SEM-EDX analysis, XRD analysis, and AAS analysis. RFW catalyst contains 60.19% (in wt) of iron, in form of magnetite (Fe3O4), hematite (Fe2O3), and wustite (FeO). RFW catalyse Fenton oxidation of MO was investigated under various experimental conditions as follows: catalyst dosage (0.5-1.5 g/L), oxidant dosage (3.3-26.4 mM), pollutant concentration (10-200 ppm), pH (2-4), and temperature (30-60◦C). Decolourisation of MO was improved by high catalyst dosage, acidic solution, and high temperature. Decolourisation up to 97% in 3 hours was observed at 0.75 g/L RFW catalyst, 6.6 mM H2O2, solution pH at 3, and temperature at 60◦C. Evaluation of iron leaching suggests that the Fenton oxidation of MO was due to the concomitant reaction of the heterogeneous and homogeneous pathway.
format article
author Sandyanto Adityosulindro
Amadira Rahdhani
Djoko M. Hartono
author_facet Sandyanto Adityosulindro
Amadira Rahdhani
Djoko M. Hartono
author_sort Sandyanto Adityosulindro
title Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water
title_short Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water
title_full Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water
title_fullStr Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water
title_full_unstemmed Heterogeneous Fenton Oxidation Catalysed by Rebar Flakes Waste for Removal of Methyl Orange in Water
title_sort heterogeneous fenton oxidation catalysed by rebar flakes waste for removal of methyl orange in water
publisher Tamkang University Press
publishDate 2021
url https://doaj.org/article/6e72de44f16641998f2685ea0f46edea
work_keys_str_mv AT sandyantoadityosulindro heterogeneousfentonoxidationcatalysedbyrebarflakeswasteforremovalofmethylorangeinwater
AT amadirarahdhani heterogeneousfentonoxidationcatalysedbyrebarflakeswasteforremovalofmethylorangeinwater
AT djokomhartono heterogeneousfentonoxidationcatalysedbyrebarflakeswasteforremovalofmethylorangeinwater
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