Band gap closure, incommensurability and molecular dissociation of dense chlorine
Molecular systems are predicted to transform into atomic solids and be metallic at high pressure; this was observed for the diatomic elements iodine and bromine. Here the authors access the higher pressures needed to observe the dissociation in chlorine, through an incommensurate phase, and provide...
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Nature Portfolio
2019
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oai:doaj.org-article:6e8240d312e94a9d91cf96adb7c19c882021-12-02T16:57:11ZBand gap closure, incommensurability and molecular dissociation of dense chlorine10.1038/s41467-019-09108-x2041-1723https://doaj.org/article/6e8240d312e94a9d91cf96adb7c19c882019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09108-xhttps://doaj.org/toc/2041-1723Molecular systems are predicted to transform into atomic solids and be metallic at high pressure; this was observed for the diatomic elements iodine and bromine. Here the authors access the higher pressures needed to observe the dissociation in chlorine, through an incommensurate phase, and provide evidence for metallization.Philip Dalladay-SimpsonJack BinnsMiriam Peña-AlvarezMary-Ellen DonnellyEran GreenbergVitali PrakapenkaXiao-Jia ChenEugene GregoryanzRoss T. HowieNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-7 (2019) |
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Science Q Philip Dalladay-Simpson Jack Binns Miriam Peña-Alvarez Mary-Ellen Donnelly Eran Greenberg Vitali Prakapenka Xiao-Jia Chen Eugene Gregoryanz Ross T. Howie Band gap closure, incommensurability and molecular dissociation of dense chlorine |
description |
Molecular systems are predicted to transform into atomic solids and be metallic at high pressure; this was observed for the diatomic elements iodine and bromine. Here the authors access the higher pressures needed to observe the dissociation in chlorine, through an incommensurate phase, and provide evidence for metallization. |
format |
article |
author |
Philip Dalladay-Simpson Jack Binns Miriam Peña-Alvarez Mary-Ellen Donnelly Eran Greenberg Vitali Prakapenka Xiao-Jia Chen Eugene Gregoryanz Ross T. Howie |
author_facet |
Philip Dalladay-Simpson Jack Binns Miriam Peña-Alvarez Mary-Ellen Donnelly Eran Greenberg Vitali Prakapenka Xiao-Jia Chen Eugene Gregoryanz Ross T. Howie |
author_sort |
Philip Dalladay-Simpson |
title |
Band gap closure, incommensurability and molecular dissociation of dense chlorine |
title_short |
Band gap closure, incommensurability and molecular dissociation of dense chlorine |
title_full |
Band gap closure, incommensurability and molecular dissociation of dense chlorine |
title_fullStr |
Band gap closure, incommensurability and molecular dissociation of dense chlorine |
title_full_unstemmed |
Band gap closure, incommensurability and molecular dissociation of dense chlorine |
title_sort |
band gap closure, incommensurability and molecular dissociation of dense chlorine |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/6e8240d312e94a9d91cf96adb7c19c88 |
work_keys_str_mv |
AT philipdalladaysimpson bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT jackbinns bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT miriampenaalvarez bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT maryellendonnelly bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT erangreenberg bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT vitaliprakapenka bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT xiaojiachen bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT eugenegregoryanz bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine AT rossthowie bandgapclosureincommensurabilityandmoleculardissociationofdensechlorine |
_version_ |
1718382571250778112 |