Synthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions

Nitrate and phosphate are major threats for water/ wastewater which grounds eutrophication's and methemoglobinemia diseases, respectively and also severely hazards the safety of aquatic beings and public health's. To deal with the purging of aqueous nitrate and phosphate contamination, a l...

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Autores principales: Hyder Ali Thagira Banu, Perumal Karthikeyan, Sankaran Meenakshi
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Lenguaje:EN
Publicado: KeAi Communications Co., Ltd. 2021
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spelling oai:doaj.org-article:6e8323d269cc4b2288e59e8c91a9696b2021-11-16T04:11:08ZSynthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions2590-182610.1016/j.enceco.2020.11.002https://doaj.org/article/6e8323d269cc4b2288e59e8c91a9696b2021-01-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2590182620300412https://doaj.org/toc/2590-1826Nitrate and phosphate are major threats for water/ wastewater which grounds eutrophication's and methemoglobinemia diseases, respectively and also severely hazards the safety of aquatic beings and public health's. To deal with the purging of aqueous nitrate and phosphate contamination, a low-cost Ce(III) decorated Duolite A 368 Plus resins (Ce-DA) were used. The influence of various adsorption factors was studied, such as adsorbent dosage, shaking time, pH, initial concentrations of nitrate and phosphate ions, competitive co-ions, isotherms and kinetic studies at different experimental temperatures etc. Ce-DA resin formed complexation with target nitrate and phosphate ions by adsorption via ion exchange and electrostatic attractions. Results from nitrate and phosphate adsorption showed that Ce-DA was greatly pH adjustable with an optimum pH of 3 to 7. The kinetic study revealed the pseudo-second-order and the Langmuir isotherm assessed a maximum adsorption efficiency of 138.67 and 156.26 mg/g for nitrate and phosphate ions respectively, which was higher than unloaded DA resin. The adsorption-desorption operations, demonstrating a great recovering performance of the adsorbent upto five successive cycles. This work highlights the cost-effective method to prepare promising adsorbent for efficient removal of toxic ions nitrate and phosphate from water.Hyder Ali Thagira BanuPerumal KarthikeyanSankaran MeenakshiKeAi Communications Co., Ltd.articleResinAdsorptionIsothermNitratePhosphateEnvironmental technology. Sanitary engineeringTD1-1066ENEnvironmental Chemistry and Ecotoxicology, Vol 3, Iss , Pp 8-16 (2021)
institution DOAJ
collection DOAJ
language EN
topic Resin
Adsorption
Isotherm
Nitrate
Phosphate
Environmental technology. Sanitary engineering
TD1-1066
spellingShingle Resin
Adsorption
Isotherm
Nitrate
Phosphate
Environmental technology. Sanitary engineering
TD1-1066
Hyder Ali Thagira Banu
Perumal Karthikeyan
Sankaran Meenakshi
Synthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions
description Nitrate and phosphate are major threats for water/ wastewater which grounds eutrophication's and methemoglobinemia diseases, respectively and also severely hazards the safety of aquatic beings and public health's. To deal with the purging of aqueous nitrate and phosphate contamination, a low-cost Ce(III) decorated Duolite A 368 Plus resins (Ce-DA) were used. The influence of various adsorption factors was studied, such as adsorbent dosage, shaking time, pH, initial concentrations of nitrate and phosphate ions, competitive co-ions, isotherms and kinetic studies at different experimental temperatures etc. Ce-DA resin formed complexation with target nitrate and phosphate ions by adsorption via ion exchange and electrostatic attractions. Results from nitrate and phosphate adsorption showed that Ce-DA was greatly pH adjustable with an optimum pH of 3 to 7. The kinetic study revealed the pseudo-second-order and the Langmuir isotherm assessed a maximum adsorption efficiency of 138.67 and 156.26 mg/g for nitrate and phosphate ions respectively, which was higher than unloaded DA resin. The adsorption-desorption operations, demonstrating a great recovering performance of the adsorbent upto five successive cycles. This work highlights the cost-effective method to prepare promising adsorbent for efficient removal of toxic ions nitrate and phosphate from water.
format article
author Hyder Ali Thagira Banu
Perumal Karthikeyan
Sankaran Meenakshi
author_facet Hyder Ali Thagira Banu
Perumal Karthikeyan
Sankaran Meenakshi
author_sort Hyder Ali Thagira Banu
title Synthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions
title_short Synthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions
title_full Synthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions
title_fullStr Synthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions
title_full_unstemmed Synthesis and characterization of Ce(III) decorated Duolite resin and its removal performance of toxic anions from aqueous solutions
title_sort synthesis and characterization of ce(iii) decorated duolite resin and its removal performance of toxic anions from aqueous solutions
publisher KeAi Communications Co., Ltd.
publishDate 2021
url https://doaj.org/article/6e8323d269cc4b2288e59e8c91a9696b
work_keys_str_mv AT hyderalithagirabanu synthesisandcharacterizationofceiiidecoratedduoliteresinanditsremovalperformanceoftoxicanionsfromaqueoussolutions
AT perumalkarthikeyan synthesisandcharacterizationofceiiidecoratedduoliteresinanditsremovalperformanceoftoxicanionsfromaqueoussolutions
AT sankaranmeenakshi synthesisandcharacterizationofceiiidecoratedduoliteresinanditsremovalperformanceoftoxicanionsfromaqueoussolutions
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