Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes

Highly enantioselective synthesis of allenes has been relying, so far, on the steric hindrance of substrates. Here the authors achieve excellent stereocontrol in the synthesis of chiral allenes with a palladium-DTBM-SEGPHOS catalytic system in a non-substrate-dependent manner.

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Main Authors:	Shihua Song, Jing Zhou, Chunling Fu, Shengming Ma
Format:	article
Language:	EN
Published:	Nature Portfolio 2019
Subjects:	Science Q
Online Access:	https://doaj.org/article/6ea835ae1b0b4f5f95dfba7ff6028b31
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spelling	oai:doaj.org-article:6ea835ae1b0b4f5f95dfba7ff6028b312021-12-02T15:35:16ZCatalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes10.1038/s41467-018-07908-12041-1723https://doaj.org/article/6ea835ae1b0b4f5f95dfba7ff6028b312019-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07908-1https://doaj.org/toc/2041-1723Highly enantioselective synthesis of allenes has been relying, so far, on the steric hindrance of substrates. Here the authors achieve excellent stereocontrol in the synthesis of chiral allenes with a palladium-DTBM-SEGPHOS catalytic system in a non-substrate-dependent manner.Shihua SongJing ZhouChunling FuShengming MaNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Shihua Song Jing Zhou Chunling Fu Shengming Ma Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
description	Highly enantioselective synthesis of allenes has been relying, so far, on the steric hindrance of substrates. Here the authors achieve excellent stereocontrol in the synthesis of chiral allenes with a palladium-DTBM-SEGPHOS catalytic system in a non-substrate-dependent manner.
format	article
author	Shihua Song Jing Zhou Chunling Fu Shengming Ma
author_facet	Shihua Song Jing Zhou Chunling Fu Shengming Ma
author_sort	Shihua Song
title	Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
title_short	Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
title_full	Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
title_fullStr	Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
title_full_unstemmed	Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
title_sort	catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/6ea835ae1b0b4f5f95dfba7ff6028b31
work_keys_str_mv	AT shihuasong catalyticenantioselectiveconstructionofaxialchiralityin13disubstitutedallenes AT jingzhou catalyticenantioselectiveconstructionofaxialchiralityin13disubstitutedallenes AT chunlingfu catalyticenantioselectiveconstructionofaxialchiralityin13disubstitutedallenes AT shengmingma catalyticenantioselectiveconstructionofaxialchiralityin13disubstitutedallenes
_version_	1718386602527424512

Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes

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