Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions

Dioxolenium ion intermediates formed from remote positions are hypothesized to direct stereoselective glycosylations. Herein we combine infrared ion spectroscopy, DFT calculations and synthetic work to characterize and study these dioxolenium ions and their role in stereoselective glycosylation reac...

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Autores principales:	Thomas Hansen, Hidde Elferink, Jacob M. A. van Hengst, Kas J. Houthuijs, Wouter A. Remmerswaal, Alexandra Kromm, Giel Berden, Stefan van der Vorm, Anouk M. Rijs, Hermen S. Overkleeft, Dmitri V. Filippov, Floris P. J. T. Rutjes, Gijsbert A. van der Marel, Jonathan Martens, Jos Oomens, Jeroen D. C. Codée, Thomas J. Boltje
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6ec49b5d3eff4a6ea8a8b5a70ecb1904
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spelling	oai:doaj.org-article:6ec49b5d3eff4a6ea8a8b5a70ecb19042021-12-02T14:47:29ZCharacterization of glycosyl dioxolenium ions and their role in glycosylation reactions10.1038/s41467-020-16362-x2041-1723https://doaj.org/article/6ec49b5d3eff4a6ea8a8b5a70ecb19042020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-16362-xhttps://doaj.org/toc/2041-1723Dioxolenium ion intermediates formed from remote positions are hypothesized to direct stereoselective glycosylations. Herein we combine infrared ion spectroscopy, DFT calculations and synthetic work to characterize and study these dioxolenium ions and their role in stereoselective glycosylation reactions.Thomas HansenHidde ElferinkJacob M. A. van HengstKas J. HouthuijsWouter A. RemmerswaalAlexandra KrommGiel BerdenStefan van der VormAnouk M. RijsHermen S. OverkleeftDmitri V. FilippovFloris P. J. T. RutjesGijsbert A. van der MarelJonathan MartensJos OomensJeroen D. C. CodéeThomas J. BoltjeNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Thomas Hansen Hidde Elferink Jacob M. A. van Hengst Kas J. Houthuijs Wouter A. Remmerswaal Alexandra Kromm Giel Berden Stefan van der Vorm Anouk M. Rijs Hermen S. Overkleeft Dmitri V. Filippov Floris P. J. T. Rutjes Gijsbert A. van der Marel Jonathan Martens Jos Oomens Jeroen D. C. Codée Thomas J. Boltje Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions
description	Dioxolenium ion intermediates formed from remote positions are hypothesized to direct stereoselective glycosylations. Herein we combine infrared ion spectroscopy, DFT calculations and synthetic work to characterize and study these dioxolenium ions and their role in stereoselective glycosylation reactions.
format	article
author	Thomas Hansen Hidde Elferink Jacob M. A. van Hengst Kas J. Houthuijs Wouter A. Remmerswaal Alexandra Kromm Giel Berden Stefan van der Vorm Anouk M. Rijs Hermen S. Overkleeft Dmitri V. Filippov Floris P. J. T. Rutjes Gijsbert A. van der Marel Jonathan Martens Jos Oomens Jeroen D. C. Codée Thomas J. Boltje
author_facet	Thomas Hansen Hidde Elferink Jacob M. A. van Hengst Kas J. Houthuijs Wouter A. Remmerswaal Alexandra Kromm Giel Berden Stefan van der Vorm Anouk M. Rijs Hermen S. Overkleeft Dmitri V. Filippov Floris P. J. T. Rutjes Gijsbert A. van der Marel Jonathan Martens Jos Oomens Jeroen D. C. Codée Thomas J. Boltje
author_sort	Thomas Hansen
title	Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions
title_short	Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions
title_full	Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions
title_fullStr	Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions
title_full_unstemmed	Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions
title_sort	characterization of glycosyl dioxolenium ions and their role in glycosylation reactions
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/6ec49b5d3eff4a6ea8a8b5a70ecb1904
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Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions

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