Redox-active, luminescent coordination nanosheet capsules containing magnetite

Abstract Two-dimensional coordination nanosheets (CONASHs) are grown at the spherical liquid–liquid interface of a dichloromethane droplet in water to form zero-dimensional nano- and micro-capsules using a simple dropping method, a syringe-pump method, and an emulsion method. Reaction of 1,3,5-tris[...

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Autores principales:	Ryo Arai, Mengjuan Li, Ryojun Toyoda, Hiroaki Maeda, Hiroshi Nishihara
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/6ed0393109304aa8bef06b102b9c19e6
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spelling	oai:doaj.org-article:6ed0393109304aa8bef06b102b9c19e62021-12-02T18:50:44ZRedox-active, luminescent coordination nanosheet capsules containing magnetite10.1038/s41598-020-70715-62045-2322https://doaj.org/article/6ed0393109304aa8bef06b102b9c19e62020-08-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-70715-6https://doaj.org/toc/2045-2322Abstract Two-dimensional coordination nanosheets (CONASHs) are grown at the spherical liquid–liquid interface of a dichloromethane droplet in water to form zero-dimensional nano- and micro-capsules using a simple dropping method, a syringe-pump method, and an emulsion method. Reaction of 1,3,5-tris[4-(4′-2,2′:6′,2″-terpyridyl)phenyl]benzene (1) with Fe(BF4)2 affords electrochromic Fe(tpy)2 CONASH capsules and that of ligand 1 with ZnSO4 does photoluminescent Zn2(μ-O2SO2)2(tpy)2 CONASH capsules. Fe(tpy)2 CONASH capsules containing magnetite particles were produced by the syringe-pump method by adding magnetite to the aqueous phase, with the assembly and dispersion of the magnetite-containing CONASH capsules being easily controlled with a magnet. This indicates that physicochemically functional CONASH capsules are suitable for incorporating other functional materials to develop hybrid systems.Ryo AraiMengjuan LiRyojun ToyodaHiroaki MaedaHiroshi NishiharaNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 10, Iss 1, Pp 1-7 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Ryo Arai Mengjuan Li Ryojun Toyoda Hiroaki Maeda Hiroshi Nishihara Redox-active, luminescent coordination nanosheet capsules containing magnetite
description	Abstract Two-dimensional coordination nanosheets (CONASHs) are grown at the spherical liquid–liquid interface of a dichloromethane droplet in water to form zero-dimensional nano- and micro-capsules using a simple dropping method, a syringe-pump method, and an emulsion method. Reaction of 1,3,5-tris[4-(4′-2,2′:6′,2″-terpyridyl)phenyl]benzene (1) with Fe(BF4)2 affords electrochromic Fe(tpy)2 CONASH capsules and that of ligand 1 with ZnSO4 does photoluminescent Zn2(μ-O2SO2)2(tpy)2 CONASH capsules. Fe(tpy)2 CONASH capsules containing magnetite particles were produced by the syringe-pump method by adding magnetite to the aqueous phase, with the assembly and dispersion of the magnetite-containing CONASH capsules being easily controlled with a magnet. This indicates that physicochemically functional CONASH capsules are suitable for incorporating other functional materials to develop hybrid systems.
format	article
author	Ryo Arai Mengjuan Li Ryojun Toyoda Hiroaki Maeda Hiroshi Nishihara
author_facet	Ryo Arai Mengjuan Li Ryojun Toyoda Hiroaki Maeda Hiroshi Nishihara
author_sort	Ryo Arai
title	Redox-active, luminescent coordination nanosheet capsules containing magnetite
title_short	Redox-active, luminescent coordination nanosheet capsules containing magnetite
title_full	Redox-active, luminescent coordination nanosheet capsules containing magnetite
title_fullStr	Redox-active, luminescent coordination nanosheet capsules containing magnetite
title_full_unstemmed	Redox-active, luminescent coordination nanosheet capsules containing magnetite
title_sort	redox-active, luminescent coordination nanosheet capsules containing magnetite
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/6ed0393109304aa8bef06b102b9c19e6
work_keys_str_mv	AT ryoarai redoxactiveluminescentcoordinationnanosheetcapsulescontainingmagnetite AT mengjuanli redoxactiveluminescentcoordinationnanosheetcapsulescontainingmagnetite AT ryojuntoyoda redoxactiveluminescentcoordinationnanosheetcapsulescontainingmagnetite AT hiroakimaeda redoxactiveluminescentcoordinationnanosheetcapsulescontainingmagnetite AT hiroshinishihara redoxactiveluminescentcoordinationnanosheetcapsulescontainingmagnetite
_version_	1718377511483604992

Redox-active, luminescent coordination nanosheet capsules containing magnetite

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