Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping

Recently, there has been remarkable progress of the host-guest doped pure organic room-temperature phosphorescence (RTP) materials. However, it remains a great challenge to develop highly efficient host-guest doping systems. In this study, we have successfully developed a heavy atom free pure organi...

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Autores principales: Jinzhu Cao, Meng Zhang, Manjeet Singh, Zhongfu An, Lingfei Ji, Huifang Shi, Yijian Jiang
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Publicado: Frontiers Media S.A. 2021
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Acceso en línea:https://doaj.org/article/6f006e502a1147a093ad2f341f583dd4
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spelling oai:doaj.org-article:6f006e502a1147a093ad2f341f583dd42021-11-30T11:50:09ZHighly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping2296-264610.3389/fchem.2021.781294https://doaj.org/article/6f006e502a1147a093ad2f341f583dd42021-11-01T00:00:00Zhttps://www.frontiersin.org/articles/10.3389/fchem.2021.781294/fullhttps://doaj.org/toc/2296-2646Recently, there has been remarkable progress of the host-guest doped pure organic room-temperature phosphorescence (RTP) materials. However, it remains a great challenge to develop highly efficient host-guest doping systems. In this study, we have successfully developed a heavy atom free pure organic molecular doped system (benzophenone-thianthrene, respectively) with efficient RTP through a simple host-guest doping strategy. Furthermore, by optimizing the doping ratios, the host-guest material with a molar ratio of 100:1 presented an efficient RTP emission with 46% quantum efficiency and a long lifetime of up to 9.17 ms under ambient conditions. This work will provide an effective way to design new organic doping systems with RTP.Jinzhu CaoJinzhu CaoMeng ZhangManjeet SinghZhongfu AnLingfei JiHuifang ShiYijian JiangFrontiers Media S.A.articlehost-guest dopingheavy atom freeroom temperature phosphorescence (RTP)triplet statenonradiative transitionChemistryQD1-999ENFrontiers in Chemistry, Vol 9 (2021)
institution DOAJ
collection DOAJ
language EN
topic host-guest doping
heavy atom free
room temperature phosphorescence (RTP)
triplet state
nonradiative transition
Chemistry
QD1-999
spellingShingle host-guest doping
heavy atom free
room temperature phosphorescence (RTP)
triplet state
nonradiative transition
Chemistry
QD1-999
Jinzhu Cao
Jinzhu Cao
Meng Zhang
Manjeet Singh
Zhongfu An
Lingfei Ji
Huifang Shi
Yijian Jiang
Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping
description Recently, there has been remarkable progress of the host-guest doped pure organic room-temperature phosphorescence (RTP) materials. However, it remains a great challenge to develop highly efficient host-guest doping systems. In this study, we have successfully developed a heavy atom free pure organic molecular doped system (benzophenone-thianthrene, respectively) with efficient RTP through a simple host-guest doping strategy. Furthermore, by optimizing the doping ratios, the host-guest material with a molar ratio of 100:1 presented an efficient RTP emission with 46% quantum efficiency and a long lifetime of up to 9.17 ms under ambient conditions. This work will provide an effective way to design new organic doping systems with RTP.
format article
author Jinzhu Cao
Jinzhu Cao
Meng Zhang
Manjeet Singh
Zhongfu An
Lingfei Ji
Huifang Shi
Yijian Jiang
author_facet Jinzhu Cao
Jinzhu Cao
Meng Zhang
Manjeet Singh
Zhongfu An
Lingfei Ji
Huifang Shi
Yijian Jiang
author_sort Jinzhu Cao
title Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping
title_short Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping
title_full Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping
title_fullStr Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping
title_full_unstemmed Highly Efficient Heavy Atom Free Room Temperature Phosphorescence by Host-Guest Doping
title_sort highly efficient heavy atom free room temperature phosphorescence by host-guest doping
publisher Frontiers Media S.A.
publishDate 2021
url https://doaj.org/article/6f006e502a1147a093ad2f341f583dd4
work_keys_str_mv AT jinzhucao highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
AT jinzhucao highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
AT mengzhang highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
AT manjeetsingh highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
AT zhongfuan highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
AT lingfeiji highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
AT huifangshi highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
AT yijianjiang highlyefficientheavyatomfreeroomtemperaturephosphorescencebyhostguestdoping
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