In-situ alloying of TiC-FeCr cermets in manganese vapour

Conventional vacuum sintering is, in general, inappropriate for producing manganese containing cermets because high vapour pressure combined with high sintering temperature of cermets (1400â1600 °C) causes considerable Mn loss through sublimation and evaporation. Sintering in Mn-rich microatmospher...

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Autores principales: Kristjan Juhani, Märt Kolnes, Jakob Kübarsepp, Marek Tarraste, Mart Viljus
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Lenguaje:EN
Publicado: Estonian Academy Publishers 2021
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Acceso en línea:https://doaj.org/article/6f0f0a22330741b6b3bfda3ad6722efe
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spelling oai:doaj.org-article:6f0f0a22330741b6b3bfda3ad6722efe2021-11-17T17:48:21ZIn-situ alloying of TiC-FeCr cermets in manganese vapour1736-60461736-753010.3176/proc.2021.4.22https://doaj.org/article/6f0f0a22330741b6b3bfda3ad6722efe2021-11-01T00:00:00Zhttps://kirj.ee/wp-content/plugins/kirj/pub/proc-4-2021-533-539_20211112172155.pdfhttps://doaj.org/toc/1736-6046https://doaj.org/toc/1736-7530Conventional vacuum sintering is, in general, inappropriate for producing manganese containing cermets because high vapour pressure combined with high sintering temperature of cermets (1400â1600 °C) causes considerable Mn loss through sublimation and evaporation. Sintering in Mn-rich microatmosphere does not only prevent Mn loss but also enables additional in-situ alloying of the binder phase during sintering. We studied alloying of TiC-based cermets bonded with high chromium steels, especially TiC-FeCr and TiC-FeCrMn, during sintering in Mn-rich atmosphere. Sintering in manganese vapour was detected to increase sinterability of the cermets, resulting in the formation of a ~1 mm thick Mn-rich surface layer with homogeneous microstructure while the core region of the material remained unaffected. This surface region of sintered TiC-FeCr and TiC-FeCrMn cermets exhibited increased Mn content and competitive mechanical properties â hardness of ~1150 HV30 and indentation fracture toughness of ~12 MPa·m1/2.Kristjan JuhaniMärt KolnesJakob KübarseppMarek TarrasteMart ViljusEstonian Academy Publishersarticletic cermetsalternative bindersintering environment.ScienceQENProceedings of the Estonian Academy of Sciences, Vol 70, Iss 4, Pp 533-539 (2021)
institution DOAJ
collection DOAJ
language EN
topic tic cermets
alternative binder
sintering environment.
Science
Q
spellingShingle tic cermets
alternative binder
sintering environment.
Science
Q
Kristjan Juhani
Märt Kolnes
Jakob Kübarsepp
Marek Tarraste
Mart Viljus
In-situ alloying of TiC-FeCr cermets in manganese vapour
description Conventional vacuum sintering is, in general, inappropriate for producing manganese containing cermets because high vapour pressure combined with high sintering temperature of cermets (1400â1600 °C) causes considerable Mn loss through sublimation and evaporation. Sintering in Mn-rich microatmosphere does not only prevent Mn loss but also enables additional in-situ alloying of the binder phase during sintering. We studied alloying of TiC-based cermets bonded with high chromium steels, especially TiC-FeCr and TiC-FeCrMn, during sintering in Mn-rich atmosphere. Sintering in manganese vapour was detected to increase sinterability of the cermets, resulting in the formation of a ~1 mm thick Mn-rich surface layer with homogeneous microstructure while the core region of the material remained unaffected. This surface region of sintered TiC-FeCr and TiC-FeCrMn cermets exhibited increased Mn content and competitive mechanical properties â hardness of ~1150 HV30 and indentation fracture toughness of ~12 MPa·m1/2.
format article
author Kristjan Juhani
Märt Kolnes
Jakob Kübarsepp
Marek Tarraste
Mart Viljus
author_facet Kristjan Juhani
Märt Kolnes
Jakob Kübarsepp
Marek Tarraste
Mart Viljus
author_sort Kristjan Juhani
title In-situ alloying of TiC-FeCr cermets in manganese vapour
title_short In-situ alloying of TiC-FeCr cermets in manganese vapour
title_full In-situ alloying of TiC-FeCr cermets in manganese vapour
title_fullStr In-situ alloying of TiC-FeCr cermets in manganese vapour
title_full_unstemmed In-situ alloying of TiC-FeCr cermets in manganese vapour
title_sort in-situ alloying of tic-fecr cermets in manganese vapour
publisher Estonian Academy Publishers
publishDate 2021
url https://doaj.org/article/6f0f0a22330741b6b3bfda3ad6722efe
work_keys_str_mv AT kristjanjuhani insitualloyingofticfecrcermetsinmanganesevapour
AT martkolnes insitualloyingofticfecrcermetsinmanganesevapour
AT jakobkubarsepp insitualloyingofticfecrcermetsinmanganesevapour
AT marektarraste insitualloyingofticfecrcermetsinmanganesevapour
AT martviljus insitualloyingofticfecrcermetsinmanganesevapour
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