Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans

Cross-dehydrogenative coupling is finding increasing application in synthesis, but coupling two chemically distinct sites remains a challenge. Here, the authors report an oxidative coupling between sp 2 and sp 3 carbons by sequentially activating the more active aryl site followed by the alkyl posit...

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Autores principales:	Jiang-Ling Shi, Ding Wang, Xi-Sha Zhang, Xiao-Lei Li, Yu-Qin Chen, Yu-Xue Li, Zhang-Jie Shi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/6f27296a57c8467b9bc947ba878315a6
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spelling	oai:doaj.org-article:6f27296a57c8467b9bc947ba878315a62021-12-02T10:48:19ZOxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans10.1038/s41467-017-00078-62041-1723https://doaj.org/article/6f27296a57c8467b9bc947ba878315a62017-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00078-6https://doaj.org/toc/2041-1723Cross-dehydrogenative coupling is finding increasing application in synthesis, but coupling two chemically distinct sites remains a challenge. Here, the authors report an oxidative coupling between sp 2 and sp 3 carbons by sequentially activating the more active aryl site followed by the alkyl position.Jiang-Ling ShiDing WangXi-Sha ZhangXiao-Lei LiYu-Qin ChenYu-Xue LiZhang-Jie ShiNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jiang-Ling Shi Ding Wang Xi-Sha Zhang Xiao-Lei Li Yu-Qin Chen Yu-Xue Li Zhang-Jie Shi Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
description	Cross-dehydrogenative coupling is finding increasing application in synthesis, but coupling two chemically distinct sites remains a challenge. Here, the authors report an oxidative coupling between sp 2 and sp 3 carbons by sequentially activating the more active aryl site followed by the alkyl position.
format	article
author	Jiang-Ling Shi Ding Wang Xi-Sha Zhang Xiao-Lei Li Yu-Qin Chen Yu-Xue Li Zhang-Jie Shi
author_facet	Jiang-Ling Shi Ding Wang Xi-Sha Zhang Xiao-Lei Li Yu-Qin Chen Yu-Xue Li Zhang-Jie Shi
author_sort	Jiang-Ling Shi
title	Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
title_short	Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
title_full	Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
title_fullStr	Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
title_full_unstemmed	Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
title_sort	oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/6f27296a57c8467b9bc947ba878315a6
work_keys_str_mv	AT jianglingshi oxidativecouplingofsp2andsp3carbonhydrogenbondstoconstructdihydrobenzofurans AT dingwang oxidativecouplingofsp2andsp3carbonhydrogenbondstoconstructdihydrobenzofurans AT xishazhang oxidativecouplingofsp2andsp3carbonhydrogenbondstoconstructdihydrobenzofurans AT xiaoleili oxidativecouplingofsp2andsp3carbonhydrogenbondstoconstructdihydrobenzofurans AT yuqinchen oxidativecouplingofsp2andsp3carbonhydrogenbondstoconstructdihydrobenzofurans AT yuxueli oxidativecouplingofsp2andsp3carbonhydrogenbondstoconstructdihydrobenzofurans AT zhangjieshi oxidativecouplingofsp2andsp3carbonhydrogenbondstoconstructdihydrobenzofurans
_version_	1718396654230437888

Oxidative coupling of sp 2 and sp 3 carbon–hydrogen bonds to construct dihydrobenzofurans

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