Aquathermolysis of heavy crude oil with ferric oleate catalyst
Abstract Oil-soluble catalysts could be of special significance for reducing the viscosity of heavy crude oil, because of their good dispersion in crude oil and high catalytic efficiency toward aquathermolysis. Ferric oleate was synthesized and applied as catalyst in the aquathermolysis reaction of...
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KeAi Communications Co., Ltd.
2018
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oai:doaj.org-article:6f31583930dd479889c8d23b3df67d6f2021-12-02T01:54:35ZAquathermolysis of heavy crude oil with ferric oleate catalyst10.1007/s12182-018-0246-x1672-51071995-8226https://doaj.org/article/6f31583930dd479889c8d23b3df67d6f2018-07-01T00:00:00Zhttp://link.springer.com/article/10.1007/s12182-018-0246-xhttps://doaj.org/toc/1672-5107https://doaj.org/toc/1995-8226Abstract Oil-soluble catalysts could be of special significance for reducing the viscosity of heavy crude oil, because of their good dispersion in crude oil and high catalytic efficiency toward aquathermolysis. Ferric oleate was synthesized and applied as catalyst in the aquathermolysis reaction of Shengli heavy oil. It was found that ferric oleate was more efficient for heavy oil cracking than Co and Ni oleates. Besides, it was superior to oleic acid and inorganic ferric nitrate and achieved the highest viscosity reduction rate of up to 86.1%. In addition, the changes in the components of Shengli heavy oil before and after aquathermolysis were investigated by elemental analysis, Fourier transform infrared spectrometry, and 1H nuclear magnetic resonance spectroscopy. Results indicated that ferric oleate contributed to a significant increase in the content of light components and decrease in the content of resin, N and S. The as-prepared ferric oleate showed good activity for reducing the viscosity and improving the quality of the heavy crude oil, showing promising application potential in aquathermolysis of heavy crude oil.Yun-Rui LiQiu-Ye LiXiao-Dong WangLai-Gui YuJian-Jun YangKeAi Communications Co., Ltd.articleHeavy oilViscosity reductionAquathermolysisFerric oleateCatalystScienceQPetrologyQE420-499ENPetroleum Science, Vol 15, Iss 3, Pp 613-624 (2018) |
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Heavy oil Viscosity reduction Aquathermolysis Ferric oleate Catalyst Science Q Petrology QE420-499 |
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Heavy oil Viscosity reduction Aquathermolysis Ferric oleate Catalyst Science Q Petrology QE420-499 Yun-Rui Li Qiu-Ye Li Xiao-Dong Wang Lai-Gui Yu Jian-Jun Yang Aquathermolysis of heavy crude oil with ferric oleate catalyst |
description |
Abstract Oil-soluble catalysts could be of special significance for reducing the viscosity of heavy crude oil, because of their good dispersion in crude oil and high catalytic efficiency toward aquathermolysis. Ferric oleate was synthesized and applied as catalyst in the aquathermolysis reaction of Shengli heavy oil. It was found that ferric oleate was more efficient for heavy oil cracking than Co and Ni oleates. Besides, it was superior to oleic acid and inorganic ferric nitrate and achieved the highest viscosity reduction rate of up to 86.1%. In addition, the changes in the components of Shengli heavy oil before and after aquathermolysis were investigated by elemental analysis, Fourier transform infrared spectrometry, and 1H nuclear magnetic resonance spectroscopy. Results indicated that ferric oleate contributed to a significant increase in the content of light components and decrease in the content of resin, N and S. The as-prepared ferric oleate showed good activity for reducing the viscosity and improving the quality of the heavy crude oil, showing promising application potential in aquathermolysis of heavy crude oil. |
format |
article |
author |
Yun-Rui Li Qiu-Ye Li Xiao-Dong Wang Lai-Gui Yu Jian-Jun Yang |
author_facet |
Yun-Rui Li Qiu-Ye Li Xiao-Dong Wang Lai-Gui Yu Jian-Jun Yang |
author_sort |
Yun-Rui Li |
title |
Aquathermolysis of heavy crude oil with ferric oleate catalyst |
title_short |
Aquathermolysis of heavy crude oil with ferric oleate catalyst |
title_full |
Aquathermolysis of heavy crude oil with ferric oleate catalyst |
title_fullStr |
Aquathermolysis of heavy crude oil with ferric oleate catalyst |
title_full_unstemmed |
Aquathermolysis of heavy crude oil with ferric oleate catalyst |
title_sort |
aquathermolysis of heavy crude oil with ferric oleate catalyst |
publisher |
KeAi Communications Co., Ltd. |
publishDate |
2018 |
url |
https://doaj.org/article/6f31583930dd479889c8d23b3df67d6f |
work_keys_str_mv |
AT yunruili aquathermolysisofheavycrudeoilwithferricoleatecatalyst AT qiuyeli aquathermolysisofheavycrudeoilwithferricoleatecatalyst AT xiaodongwang aquathermolysisofheavycrudeoilwithferricoleatecatalyst AT laiguiyu aquathermolysisofheavycrudeoilwithferricoleatecatalyst AT jianjunyang aquathermolysisofheavycrudeoilwithferricoleatecatalyst |
_version_ |
1718402845029433344 |