Aquathermolysis of heavy crude oil with ferric oleate catalyst

Abstract Oil-soluble catalysts could be of special significance for reducing the viscosity of heavy crude oil, because of their good dispersion in crude oil and high catalytic efficiency toward aquathermolysis. Ferric oleate was synthesized and applied as catalyst in the aquathermolysis reaction of...

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Autores principales: Yun-Rui Li, Qiu-Ye Li, Xiao-Dong Wang, Lai-Gui Yu, Jian-Jun Yang
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Lenguaje:EN
Publicado: KeAi Communications Co., Ltd. 2018
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Acceso en línea:https://doaj.org/article/6f31583930dd479889c8d23b3df67d6f
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spelling oai:doaj.org-article:6f31583930dd479889c8d23b3df67d6f2021-12-02T01:54:35ZAquathermolysis of heavy crude oil with ferric oleate catalyst10.1007/s12182-018-0246-x1672-51071995-8226https://doaj.org/article/6f31583930dd479889c8d23b3df67d6f2018-07-01T00:00:00Zhttp://link.springer.com/article/10.1007/s12182-018-0246-xhttps://doaj.org/toc/1672-5107https://doaj.org/toc/1995-8226Abstract Oil-soluble catalysts could be of special significance for reducing the viscosity of heavy crude oil, because of their good dispersion in crude oil and high catalytic efficiency toward aquathermolysis. Ferric oleate was synthesized and applied as catalyst in the aquathermolysis reaction of Shengli heavy oil. It was found that ferric oleate was more efficient for heavy oil cracking than Co and Ni oleates. Besides, it was superior to oleic acid and inorganic ferric nitrate and achieved the highest viscosity reduction rate of up to 86.1%. In addition, the changes in the components of Shengli heavy oil before and after aquathermolysis were investigated by elemental analysis, Fourier transform infrared spectrometry, and 1H nuclear magnetic resonance spectroscopy. Results indicated that ferric oleate contributed to a significant increase in the content of light components and decrease in the content of resin, N and S. The as-prepared ferric oleate showed good activity for reducing the viscosity and improving the quality of the heavy crude oil, showing promising application potential in aquathermolysis of heavy crude oil.Yun-Rui LiQiu-Ye LiXiao-Dong WangLai-Gui YuJian-Jun YangKeAi Communications Co., Ltd.articleHeavy oilViscosity reductionAquathermolysisFerric oleateCatalystScienceQPetrologyQE420-499ENPetroleum Science, Vol 15, Iss 3, Pp 613-624 (2018)
institution DOAJ
collection DOAJ
language EN
topic Heavy oil
Viscosity reduction
Aquathermolysis
Ferric oleate
Catalyst
Science
Q
Petrology
QE420-499
spellingShingle Heavy oil
Viscosity reduction
Aquathermolysis
Ferric oleate
Catalyst
Science
Q
Petrology
QE420-499
Yun-Rui Li
Qiu-Ye Li
Xiao-Dong Wang
Lai-Gui Yu
Jian-Jun Yang
Aquathermolysis of heavy crude oil with ferric oleate catalyst
description Abstract Oil-soluble catalysts could be of special significance for reducing the viscosity of heavy crude oil, because of their good dispersion in crude oil and high catalytic efficiency toward aquathermolysis. Ferric oleate was synthesized and applied as catalyst in the aquathermolysis reaction of Shengli heavy oil. It was found that ferric oleate was more efficient for heavy oil cracking than Co and Ni oleates. Besides, it was superior to oleic acid and inorganic ferric nitrate and achieved the highest viscosity reduction rate of up to 86.1%. In addition, the changes in the components of Shengli heavy oil before and after aquathermolysis were investigated by elemental analysis, Fourier transform infrared spectrometry, and 1H nuclear magnetic resonance spectroscopy. Results indicated that ferric oleate contributed to a significant increase in the content of light components and decrease in the content of resin, N and S. The as-prepared ferric oleate showed good activity for reducing the viscosity and improving the quality of the heavy crude oil, showing promising application potential in aquathermolysis of heavy crude oil.
format article
author Yun-Rui Li
Qiu-Ye Li
Xiao-Dong Wang
Lai-Gui Yu
Jian-Jun Yang
author_facet Yun-Rui Li
Qiu-Ye Li
Xiao-Dong Wang
Lai-Gui Yu
Jian-Jun Yang
author_sort Yun-Rui Li
title Aquathermolysis of heavy crude oil with ferric oleate catalyst
title_short Aquathermolysis of heavy crude oil with ferric oleate catalyst
title_full Aquathermolysis of heavy crude oil with ferric oleate catalyst
title_fullStr Aquathermolysis of heavy crude oil with ferric oleate catalyst
title_full_unstemmed Aquathermolysis of heavy crude oil with ferric oleate catalyst
title_sort aquathermolysis of heavy crude oil with ferric oleate catalyst
publisher KeAi Communications Co., Ltd.
publishDate 2018
url https://doaj.org/article/6f31583930dd479889c8d23b3df67d6f
work_keys_str_mv AT yunruili aquathermolysisofheavycrudeoilwithferricoleatecatalyst
AT qiuyeli aquathermolysisofheavycrudeoilwithferricoleatecatalyst
AT xiaodongwang aquathermolysisofheavycrudeoilwithferricoleatecatalyst
AT laiguiyu aquathermolysisofheavycrudeoilwithferricoleatecatalyst
AT jianjunyang aquathermolysisofheavycrudeoilwithferricoleatecatalyst
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