Solvent tuning of photochemistry upon excited-state symmetry breaking
Symmetric multibranched donor-acceptor molecules are promising photoactive materials for diverse applications. Here the authors show that, in octupolar and quadrupolar dyes, excited-state symmetry breaking occurs efficiently in polar solvents only and results in a concentration of the excitation tha...
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| Autores principales: | , , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2020
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/6f32ca1cc15445a0a0b86ae532240953 |
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| Sumario: | Symmetric multibranched donor-acceptor molecules are promising photoactive materials for diverse applications. Here the authors show that, in octupolar and quadrupolar dyes, excited-state symmetry breaking occurs efficiently in polar solvents only and results in a concentration of the excitation that may trigger fast photochemical reactions. |
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