Solvent tuning of photochemistry upon excited-state symmetry breaking

Solvent tuning of photochemistry upon excited-state symmetry breaking

Symmetric multibranched donor-acceptor molecules are promising photoactive materials for diverse applications. Here the authors show that, in octupolar and quadrupolar dyes, excited-state symmetry breaking occurs efficiently in polar solvents only and results in a concentration of the excitation tha...

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Autores principales: Bogdan Dereka, Denis Svechkarev, Arnulf Rosspeintner, Alexander Aster, Markus Lunzer, Robert Liska, Aaron M. Mohs, Eric Vauthey
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Q
Acceso en línea:https://doaj.org/article/6f32ca1cc15445a0a0b86ae532240953
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spelling oai:doaj.org-article:6f32ca1cc15445a0a0b86ae5322409532021-12-02T17:31:10ZSolvent tuning of photochemistry upon excited-state symmetry breaking10.1038/s41467-020-15681-32041-1723https://doaj.org/article/6f32ca1cc15445a0a0b86ae5322409532020-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15681-3https://doaj.org/toc/2041-1723Symmetric multibranched donor-acceptor molecules are promising photoactive materials for diverse applications. Here the authors show that, in octupolar and quadrupolar dyes, excited-state symmetry breaking occurs efficiently in polar solvents only and results in a concentration of the excitation that may trigger fast photochemical reactions.Bogdan DerekaDenis SvechkarevArnulf RosspeintnerAlexander AsterMarkus LunzerRobert LiskaAaron M. MohsEric VautheyNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Bogdan Dereka
Denis Svechkarev
Arnulf Rosspeintner
Alexander Aster
Markus Lunzer
Robert Liska
Aaron M. Mohs
Eric Vauthey
Solvent tuning of photochemistry upon excited-state symmetry breaking
description Symmetric multibranched donor-acceptor molecules are promising photoactive materials for diverse applications. Here the authors show that, in octupolar and quadrupolar dyes, excited-state symmetry breaking occurs efficiently in polar solvents only and results in a concentration of the excitation that may trigger fast photochemical reactions.
format article
author Bogdan Dereka
Denis Svechkarev
Arnulf Rosspeintner
Alexander Aster
Markus Lunzer
Robert Liska
Aaron M. Mohs
Eric Vauthey
author_facet Bogdan Dereka
Denis Svechkarev
Arnulf Rosspeintner
Alexander Aster
Markus Lunzer
Robert Liska
Aaron M. Mohs
Eric Vauthey
author_sort Bogdan Dereka
title Solvent tuning of photochemistry upon excited-state symmetry breaking
title_short Solvent tuning of photochemistry upon excited-state symmetry breaking
title_full Solvent tuning of photochemistry upon excited-state symmetry breaking
title_fullStr Solvent tuning of photochemistry upon excited-state symmetry breaking
title_full_unstemmed Solvent tuning of photochemistry upon excited-state symmetry breaking
title_sort solvent tuning of photochemistry upon excited-state symmetry breaking
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/6f32ca1cc15445a0a0b86ae532240953
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AT denissvechkarev solventtuningofphotochemistryuponexcitedstatesymmetrybreaking
AT arnulfrosspeintner solventtuningofphotochemistryuponexcitedstatesymmetrybreaking
AT alexanderaster solventtuningofphotochemistryuponexcitedstatesymmetrybreaking
AT markuslunzer solventtuningofphotochemistryuponexcitedstatesymmetrybreaking
AT robertliska solventtuningofphotochemistryuponexcitedstatesymmetrybreaking
AT aaronmmohs solventtuningofphotochemistryuponexcitedstatesymmetrybreaking
AT ericvauthey solventtuningofphotochemistryuponexcitedstatesymmetrybreaking
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