Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization
One of the fundamental laws in crystallization is translational symmetry but breaking translational symmetry can be used as a general route towards the design of nanostructures. Here the authors show that overcrowding in molecular bottlebrush polymers allows for spontaneous formation of spherical ho...
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Nature Portfolio
2020
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oai:doaj.org-article:6fcaf5a05ee34c37b7bcaca3803638ff2021-12-02T14:40:52ZBreaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization10.1038/s41467-020-15477-52041-1723https://doaj.org/article/6fcaf5a05ee34c37b7bcaca3803638ff2020-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15477-5https://doaj.org/toc/2041-1723One of the fundamental laws in crystallization is translational symmetry but breaking translational symmetry can be used as a general route towards the design of nanostructures. Here the authors show that overcrowding in molecular bottlebrush polymers allows for spontaneous formation of spherical hollow crystals with broken translational symmetry.Hao QiXiting LiuDaniel M. HennShan MeiMark C. StaubBin ZhaoChristopher Y. LiNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-9 (2020) |
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Science Q Hao Qi Xiting Liu Daniel M. Henn Shan Mei Mark C. Staub Bin Zhao Christopher Y. Li Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization |
description |
One of the fundamental laws in crystallization is translational symmetry but breaking translational symmetry can be used as a general route towards the design of nanostructures. Here the authors show that overcrowding in molecular bottlebrush polymers allows for spontaneous formation of spherical hollow crystals with broken translational symmetry. |
format |
article |
author |
Hao Qi Xiting Liu Daniel M. Henn Shan Mei Mark C. Staub Bin Zhao Christopher Y. Li |
author_facet |
Hao Qi Xiting Liu Daniel M. Henn Shan Mei Mark C. Staub Bin Zhao Christopher Y. Li |
author_sort |
Hao Qi |
title |
Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization |
title_short |
Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization |
title_full |
Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization |
title_fullStr |
Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization |
title_full_unstemmed |
Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization |
title_sort |
breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization |
publisher |
Nature Portfolio |
publishDate |
2020 |
url |
https://doaj.org/article/6fcaf5a05ee34c37b7bcaca3803638ff |
work_keys_str_mv |
AT haoqi breakingtranslationalsymmetryviapolymerchainovercrowdinginmolecularbottlebrushcrystallization AT xitingliu breakingtranslationalsymmetryviapolymerchainovercrowdinginmolecularbottlebrushcrystallization AT danielmhenn breakingtranslationalsymmetryviapolymerchainovercrowdinginmolecularbottlebrushcrystallization AT shanmei breakingtranslationalsymmetryviapolymerchainovercrowdinginmolecularbottlebrushcrystallization AT markcstaub breakingtranslationalsymmetryviapolymerchainovercrowdinginmolecularbottlebrushcrystallization AT binzhao breakingtranslationalsymmetryviapolymerchainovercrowdinginmolecularbottlebrushcrystallization AT christopheryli breakingtranslationalsymmetryviapolymerchainovercrowdinginmolecularbottlebrushcrystallization |
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1718390117042749440 |