N2H4 as traceless mediator for homo- and cross- aryl coupling

Synthesis of biaryls by coupling strategies is unavoidably accompanied by stoichiometric metal waste. Here, the authors report the homo- and cross-electrophile coupling by using hydrazine as metal surrogate, only liberating N2 and H2 as side products.

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Detalles Bibliográficos
Autores principales: Leiyang Lv, Zihang Qiu, Jianbin Li, Mingxin Liu, Chao-Jun Li
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/712363ab219a4a488d69f794dcc3573c
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Sumario:Synthesis of biaryls by coupling strategies is unavoidably accompanied by stoichiometric metal waste. Here, the authors report the homo- and cross-electrophile coupling by using hydrazine as metal surrogate, only liberating N2 and H2 as side products.