N2H4 as traceless mediator for homo- and cross- aryl coupling
Synthesis of biaryls by coupling strategies is unavoidably accompanied by stoichiometric metal waste. Here, the authors report the homo- and cross-electrophile coupling by using hydrazine as metal surrogate, only liberating N2 and H2 as side products.
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Nature Portfolio
2018
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oai:doaj.org-article:712363ab219a4a488d69f794dcc3573c2021-12-02T16:56:36ZN2H4 as traceless mediator for homo- and cross- aryl coupling10.1038/s41467-018-07198-72041-1723https://doaj.org/article/712363ab219a4a488d69f794dcc3573c2018-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07198-7https://doaj.org/toc/2041-1723Synthesis of biaryls by coupling strategies is unavoidably accompanied by stoichiometric metal waste. Here, the authors report the homo- and cross-electrophile coupling by using hydrazine as metal surrogate, only liberating N2 and H2 as side products.Leiyang LvZihang QiuJianbin LiMingxin LiuChao-Jun LiNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-11 (2018) |
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Science Q Leiyang Lv Zihang Qiu Jianbin Li Mingxin Liu Chao-Jun Li N2H4 as traceless mediator for homo- and cross- aryl coupling |
description |
Synthesis of biaryls by coupling strategies is unavoidably accompanied by stoichiometric metal waste. Here, the authors report the homo- and cross-electrophile coupling by using hydrazine as metal surrogate, only liberating N2 and H2 as side products. |
format |
article |
author |
Leiyang Lv Zihang Qiu Jianbin Li Mingxin Liu Chao-Jun Li |
author_facet |
Leiyang Lv Zihang Qiu Jianbin Li Mingxin Liu Chao-Jun Li |
author_sort |
Leiyang Lv |
title |
N2H4 as traceless mediator for homo- and cross- aryl coupling |
title_short |
N2H4 as traceless mediator for homo- and cross- aryl coupling |
title_full |
N2H4 as traceless mediator for homo- and cross- aryl coupling |
title_fullStr |
N2H4 as traceless mediator for homo- and cross- aryl coupling |
title_full_unstemmed |
N2H4 as traceless mediator for homo- and cross- aryl coupling |
title_sort |
n2h4 as traceless mediator for homo- and cross- aryl coupling |
publisher |
Nature Portfolio |
publishDate |
2018 |
url |
https://doaj.org/article/712363ab219a4a488d69f794dcc3573c |
work_keys_str_mv |
AT leiyanglv n2h4astracelessmediatorforhomoandcrossarylcoupling AT zihangqiu n2h4astracelessmediatorforhomoandcrossarylcoupling AT jianbinli n2h4astracelessmediatorforhomoandcrossarylcoupling AT mingxinliu n2h4astracelessmediatorforhomoandcrossarylcoupling AT chaojunli n2h4astracelessmediatorforhomoandcrossarylcoupling |
_version_ |
1718382805188083712 |