Real–time observation of interfacial ions during electrocrystallization

Abstract Understanding the electrocrystallization mechanisms of metal cations is of importance for many industrial and scientific fields. We have determined the transitional structures during underpotential deposition (upd) of various metal cations on Au(111) electrode using time–resolved surface X–...

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Autores principales:	Masashi Nakamura, Takahiro Banzai, Yuto Maehata, Osamu Endo, Hiroo Tajiri, Osami Sakata, Nagahiro Hoshi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/71321d6b637148a1a216fdbde9f2e39f
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spelling	oai:doaj.org-article:71321d6b637148a1a216fdbde9f2e39f2021-12-02T12:32:46ZReal–time observation of interfacial ions during electrocrystallization10.1038/s41598-017-01048-02045-2322https://doaj.org/article/71321d6b637148a1a216fdbde9f2e39f2017-04-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-01048-0https://doaj.org/toc/2045-2322Abstract Understanding the electrocrystallization mechanisms of metal cations is of importance for many industrial and scientific fields. We have determined the transitional structures during underpotential deposition (upd) of various metal cations on Au(111) electrode using time–resolved surface X–ray diffraction and step–scan IR spectroscopy. At the initial stage of upd, a characteristic intensity transient appears in the time–resolved crystal truncation rod depending on metal cations. Metal cations with relatively high coordination energies of hydration water are deposited in two steps: first, the hydrated metal cations approached the surface and are metastably located at the outer Helmholtz plane, then they are deposited via the destruction of the hydration shell. However, Tl+ and Ag+, which have low hydration energy, are rapidly adsorbed on Au(111) electrode without any metastable states of dehydration. Therefore, the deposition rate is strongly related to the coordination energy of the hydration water. Metal cations strongly interacting with the counter coadsorbed anions such as Cu2+ in sulfuric acid causes the deposition rate to be slower because of the formation of complexes.Masashi NakamuraTakahiro BanzaiYuto MaehataOsamu EndoHiroo TajiriOsami SakataNagahiro HoshiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-9 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Masashi Nakamura Takahiro Banzai Yuto Maehata Osamu Endo Hiroo Tajiri Osami Sakata Nagahiro Hoshi Real–time observation of interfacial ions during electrocrystallization
description	Abstract Understanding the electrocrystallization mechanisms of metal cations is of importance for many industrial and scientific fields. We have determined the transitional structures during underpotential deposition (upd) of various metal cations on Au(111) electrode using time–resolved surface X–ray diffraction and step–scan IR spectroscopy. At the initial stage of upd, a characteristic intensity transient appears in the time–resolved crystal truncation rod depending on metal cations. Metal cations with relatively high coordination energies of hydration water are deposited in two steps: first, the hydrated metal cations approached the surface and are metastably located at the outer Helmholtz plane, then they are deposited via the destruction of the hydration shell. However, Tl+ and Ag+, which have low hydration energy, are rapidly adsorbed on Au(111) electrode without any metastable states of dehydration. Therefore, the deposition rate is strongly related to the coordination energy of the hydration water. Metal cations strongly interacting with the counter coadsorbed anions such as Cu2+ in sulfuric acid causes the deposition rate to be slower because of the formation of complexes.
format	article
author	Masashi Nakamura Takahiro Banzai Yuto Maehata Osamu Endo Hiroo Tajiri Osami Sakata Nagahiro Hoshi
author_facet	Masashi Nakamura Takahiro Banzai Yuto Maehata Osamu Endo Hiroo Tajiri Osami Sakata Nagahiro Hoshi
author_sort	Masashi Nakamura
title	Real–time observation of interfacial ions during electrocrystallization
title_short	Real–time observation of interfacial ions during electrocrystallization
title_full	Real–time observation of interfacial ions during electrocrystallization
title_fullStr	Real–time observation of interfacial ions during electrocrystallization
title_full_unstemmed	Real–time observation of interfacial ions during electrocrystallization
title_sort	real–time observation of interfacial ions during electrocrystallization
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/71321d6b637148a1a216fdbde9f2e39f
work_keys_str_mv	AT masashinakamura realtimeobservationofinterfacialionsduringelectrocrystallization AT takahirobanzai realtimeobservationofinterfacialionsduringelectrocrystallization AT yutomaehata realtimeobservationofinterfacialionsduringelectrocrystallization AT osamuendo realtimeobservationofinterfacialionsduringelectrocrystallization AT hirootajiri realtimeobservationofinterfacialionsduringelectrocrystallization AT osamisakata realtimeobservationofinterfacialionsduringelectrocrystallization AT nagahirohoshi realtimeobservationofinterfacialionsduringelectrocrystallization
_version_	1718393985375928320

Real–time observation of interfacial ions during electrocrystallization

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