Evidence for a chemical clock in oscillatory formation of UiO-66

Reactions with non-linear kinetics, such as chemical clocks, are reasonably common but only well understood in the liquid phase. Here, the authors report and rationalize a chemical clock reaction taking place in a solidifying metal-organic framework.

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Detalles Bibliográficos
Autores principales: M. G. Goesten, M. F. de Lange, A. I. Olivos-Suarez, A. V. Bavykina, P. Serra-Crespo, C. Krywka, F. M. Bickelhaupt, F. Kapteijn, Jorge Gascon
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/718ddaf4c195427e80ed39b3ddaaa8b8
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Descripción
Sumario:Reactions with non-linear kinetics, such as chemical clocks, are reasonably common but only well understood in the liquid phase. Here, the authors report and rationalize a chemical clock reaction taking place in a solidifying metal-organic framework.