Proton mediated spin state transition of cobalt heme analogs

Studying the electronic structures and spin transitions of synthetic heme analogs is crucial to advancing our understanding of heme enzyme mechanisms. Here the authors show that a Co(II) porphyrin complex undergoes an unexpected spin state transition upon deprotonation of its axial imidazole ligand.

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Autores principales:	Jianping Zhao, Qian Peng, Zijian Wang, Wei Xu, Hongyan Xiao, Qi Wu, Hao-Ling Sun, Fang Ma, Jiyong Zhao, Cheng-Jun Sun, Jianzhang Zhao, Jianfeng Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/71fe878e30de42d5a9f2910b5aec1f63
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spelling	oai:doaj.org-article:71fe878e30de42d5a9f2910b5aec1f632021-12-02T17:01:51ZProton mediated spin state transition of cobalt heme analogs10.1038/s41467-019-10357-z2041-1723https://doaj.org/article/71fe878e30de42d5a9f2910b5aec1f632019-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10357-zhttps://doaj.org/toc/2041-1723Studying the electronic structures and spin transitions of synthetic heme analogs is crucial to advancing our understanding of heme enzyme mechanisms. Here the authors show that a Co(II) porphyrin complex undergoes an unexpected spin state transition upon deprotonation of its axial imidazole ligand.Jianping ZhaoQian PengZijian WangWei XuHongyan XiaoQi WuHao-Ling SunFang MaJiyong ZhaoCheng-Jun SunJianzhang ZhaoJianfeng LiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jianping Zhao Qian Peng Zijian Wang Wei Xu Hongyan Xiao Qi Wu Hao-Ling Sun Fang Ma Jiyong Zhao Cheng-Jun Sun Jianzhang Zhao Jianfeng Li Proton mediated spin state transition of cobalt heme analogs
description	Studying the electronic structures and spin transitions of synthetic heme analogs is crucial to advancing our understanding of heme enzyme mechanisms. Here the authors show that a Co(II) porphyrin complex undergoes an unexpected spin state transition upon deprotonation of its axial imidazole ligand.
format	article
author	Jianping Zhao Qian Peng Zijian Wang Wei Xu Hongyan Xiao Qi Wu Hao-Ling Sun Fang Ma Jiyong Zhao Cheng-Jun Sun Jianzhang Zhao Jianfeng Li
author_facet	Jianping Zhao Qian Peng Zijian Wang Wei Xu Hongyan Xiao Qi Wu Hao-Ling Sun Fang Ma Jiyong Zhao Cheng-Jun Sun Jianzhang Zhao Jianfeng Li
author_sort	Jianping Zhao
title	Proton mediated spin state transition of cobalt heme analogs
title_short	Proton mediated spin state transition of cobalt heme analogs
title_full	Proton mediated spin state transition of cobalt heme analogs
title_fullStr	Proton mediated spin state transition of cobalt heme analogs
title_full_unstemmed	Proton mediated spin state transition of cobalt heme analogs
title_sort	proton mediated spin state transition of cobalt heme analogs
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/71fe878e30de42d5a9f2910b5aec1f63
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Proton mediated spin state transition of cobalt heme analogs

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