Proton mediated spin state transition of cobalt heme analogs
Studying the electronic structures and spin transitions of synthetic heme analogs is crucial to advancing our understanding of heme enzyme mechanisms. Here the authors show that a Co(II) porphyrin complex undergoes an unexpected spin state transition upon deprotonation of its axial imidazole ligand.
Enregistré dans:
Auteurs principaux: | Jianping Zhao, Qian Peng, Zijian Wang, Wei Xu, Hongyan Xiao, Qi Wu, Hao-Ling Sun, Fang Ma, Jiyong Zhao, Cheng-Jun Sun, Jianzhang Zhao, Jianfeng Li |
---|---|
Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2019
|
Sujets: | |
Accès en ligne: | https://doaj.org/article/71fe878e30de42d5a9f2910b5aec1f63 |
Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|
Documents similaires
-
Publisher Correction: Proton mediated spin state transition of cobalt heme analogs
par: Jianping Zhao, et autres
Publié: (2019) -
Ultrafast carbon monoxide photolysis and heme spin-crossover in myoglobin via nonadiabatic quantum dynamics
par: Konstantin Falahati, et autres
Publié: (2018) -
First Principles Theory of the hcp-fcc Phase Transition in Cobalt
par: Raquel Lizárraga, et autres
Publié: (2017) -
Excitation of coupled spin–orbit dynamics in cobalt oxide by femtosecond laser pulses
par: Takuya Satoh, et autres
Publié: (2017) -
Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
par: Shiming Zhou, et autres
Publié: (2016)