Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites
The paper investigates the synthesis of eco-friendly composites and their properties before and after immersion in solvents of different chemical natures. For their preparation, unsaturated polyester resin (UPR) based on recycled poly (ethylene terephthalate) (PET) and peanut shell powder (PSP) were...
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oai:doaj.org-article:726ff9e8fdfc45fdb5da03dfea3964292021-11-11T18:44:00ZEffect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites10.3390/polym132136902073-4360https://doaj.org/article/726ff9e8fdfc45fdb5da03dfea3964292021-10-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/21/3690https://doaj.org/toc/2073-4360The paper investigates the synthesis of eco-friendly composites and their properties before and after immersion in solvents of different chemical natures. For their preparation, unsaturated polyester resin (UPR) based on recycled poly (ethylene terephthalate) (PET) and peanut shell powder (PSP) were used. Polymerization was carried out in the presence of environmentally friendly polymeric cobalt. Distilled water, acetone, 10% hydrochloric acid, 40% sodium hydroxide, toluene, and 2% sodium carbonate were used as solvents in the chemical resistance test. Changes in the structure, properties, and appearance (morphology) of composites after 140 days of immersion in solvents were investigated. The results show that both the resin and its composites show resistance towards 10% HCl and toluene. The immersion in water has no significant effect on the resin, but for PSP composites, the plasticizing effect of water was observed. In acetone, after only one day, the resin and its composite with 10% PSP shrink and fall into pieces. However, the most destructive is an alkaline environment. After the immersion test, a huge increase in mass and a deterioration of gloss and thermomechanical properties were observed. The destructive influence of the 40% NaOH environment mainly concerned the resin.Przemysław PączkowskiAndrzej PuszkaBarbara GawdzikMDPI AGarticleunsaturated polyester resineco-friendlybiofillerpeanut shelllignocellulosic biomasscompositesOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3690, p 3690 (2021) |
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unsaturated polyester resin eco-friendly biofiller peanut shell lignocellulosic biomass composites Organic chemistry QD241-441 |
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unsaturated polyester resin eco-friendly biofiller peanut shell lignocellulosic biomass composites Organic chemistry QD241-441 Przemysław Pączkowski Andrzej Puszka Barbara Gawdzik Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites |
description |
The paper investigates the synthesis of eco-friendly composites and their properties before and after immersion in solvents of different chemical natures. For their preparation, unsaturated polyester resin (UPR) based on recycled poly (ethylene terephthalate) (PET) and peanut shell powder (PSP) were used. Polymerization was carried out in the presence of environmentally friendly polymeric cobalt. Distilled water, acetone, 10% hydrochloric acid, 40% sodium hydroxide, toluene, and 2% sodium carbonate were used as solvents in the chemical resistance test. Changes in the structure, properties, and appearance (morphology) of composites after 140 days of immersion in solvents were investigated. The results show that both the resin and its composites show resistance towards 10% HCl and toluene. The immersion in water has no significant effect on the resin, but for PSP composites, the plasticizing effect of water was observed. In acetone, after only one day, the resin and its composite with 10% PSP shrink and fall into pieces. However, the most destructive is an alkaline environment. After the immersion test, a huge increase in mass and a deterioration of gloss and thermomechanical properties were observed. The destructive influence of the 40% NaOH environment mainly concerned the resin. |
format |
article |
author |
Przemysław Pączkowski Andrzej Puszka Barbara Gawdzik |
author_facet |
Przemysław Pączkowski Andrzej Puszka Barbara Gawdzik |
author_sort |
Przemysław Pączkowski |
title |
Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites |
title_short |
Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites |
title_full |
Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites |
title_fullStr |
Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites |
title_full_unstemmed |
Effect of Eco-Friendly Peanut Shell Powder on the Chemical Resistance, Physical, Thermal, and Thermomechanical Properties of Unsaturated Polyester Resin Composites |
title_sort |
effect of eco-friendly peanut shell powder on the chemical resistance, physical, thermal, and thermomechanical properties of unsaturated polyester resin composites |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/726ff9e8fdfc45fdb5da03dfea396429 |
work_keys_str_mv |
AT przemysławpaczkowski effectofecofriendlypeanutshellpowderonthechemicalresistancephysicalthermalandthermomechanicalpropertiesofunsaturatedpolyesterresincomposites AT andrzejpuszka effectofecofriendlypeanutshellpowderonthechemicalresistancephysicalthermalandthermomechanicalpropertiesofunsaturatedpolyesterresincomposites AT barbaragawdzik effectofecofriendlypeanutshellpowderonthechemicalresistancephysicalthermalandthermomechanicalpropertiesofunsaturatedpolyesterresincomposites |
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1718431768299700224 |