Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate

Synthesis biopolymer of sulfonated copolymer eugenol-diallyl phthalate (PEGDAF), its characterization, and study of proton exchange polymer membrane properties had been done. This synthesis was conducted by eugenol and diallyl phthalate reaction to form PEGDAF, which is sulfonated using sulfuric aci...

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Autores principales:	Ngadiwiyana Ngadiwiyana, Nor Basid Adiwibawa Prasetya, Gunawan Gunawan, Tutuk Djoko Kusworo, Heru Susanto
Formato:	article
Lenguaje:	EN
Publicado:	Department of Chemistry, Universitas Gadjah Mada 2020
Materias:	eugenol diallyl phthalate membrane proton exchange polymer Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/729c7b47a7f047e683c8bd70cec9409d
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spelling	oai:doaj.org-article:729c7b47a7f047e683c8bd70cec9409d2021-12-02T13:24:41ZSynthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate1411-94202460-157810.22146/ijc.55353https://doaj.org/article/729c7b47a7f047e683c8bd70cec9409d2020-11-01T00:00:00Zhttps://jurnal.ugm.ac.id/ijc/article/view/55353https://doaj.org/toc/1411-9420https://doaj.org/toc/2460-1578Synthesis biopolymer of sulfonated copolymer eugenol-diallyl phthalate (PEGDAF), its characterization, and study of proton exchange polymer membrane properties had been done. This synthesis was conducted by eugenol and diallyl phthalate reaction to form PEGDAF, which is sulfonated using sulfuric acid. In addition, the functional groups of the PEGDAF and its sulfonated form were analyzed using FT-IR. Furthermore, the polymer properties were determined by measuring values of sulfonation degree, cation exchange capacity, proton conductivity, and water uptake. FT-IR spectra showed that the vinyl group had been added to the process of PEGDAF formation, while spectra deconvolution was used to confirm the occurrence of sulfonation reaction. The sulfonation of PEGDAF in 2 h optimum reaction time produces a black solid with a melting point of 133 °C in 16.55% yield. The highest proton conductivity, cation exchange capacity (CEC), and water uptake were 8.334 × 10–6 S cm–1, 0.44 meq/g, and 73.0%, respectively.Ngadiwiyana NgadiwiyanaNor Basid Adiwibawa PrasetyaGunawan GunawanTutuk Djoko KusworoHeru SusantoDepartment of Chemistry, Universitas Gadjah Madaarticleeugenoldiallyl phthalatemembraneproton exchangepolymerChemistryQD1-999ENIndonesian Journal of Chemistry, Vol 21, Iss 1, Pp 168-178 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	eugenol diallyl phthalate membrane proton exchange polymer Chemistry QD1-999
spellingShingle	eugenol diallyl phthalate membrane proton exchange polymer Chemistry QD1-999 Ngadiwiyana Ngadiwiyana Nor Basid Adiwibawa Prasetya Gunawan Gunawan Tutuk Djoko Kusworo Heru Susanto Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate
description	Synthesis biopolymer of sulfonated copolymer eugenol-diallyl phthalate (PEGDAF), its characterization, and study of proton exchange polymer membrane properties had been done. This synthesis was conducted by eugenol and diallyl phthalate reaction to form PEGDAF, which is sulfonated using sulfuric acid. In addition, the functional groups of the PEGDAF and its sulfonated form were analyzed using FT-IR. Furthermore, the polymer properties were determined by measuring values of sulfonation degree, cation exchange capacity, proton conductivity, and water uptake. FT-IR spectra showed that the vinyl group had been added to the process of PEGDAF formation, while spectra deconvolution was used to confirm the occurrence of sulfonation reaction. The sulfonation of PEGDAF in 2 h optimum reaction time produces a black solid with a melting point of 133 °C in 16.55% yield. The highest proton conductivity, cation exchange capacity (CEC), and water uptake were 8.334 × 10–6 S cm–1, 0.44 meq/g, and 73.0%, respectively.
format	article
author	Ngadiwiyana Ngadiwiyana Nor Basid Adiwibawa Prasetya Gunawan Gunawan Tutuk Djoko Kusworo Heru Susanto
author_facet	Ngadiwiyana Ngadiwiyana Nor Basid Adiwibawa Prasetya Gunawan Gunawan Tutuk Djoko Kusworo Heru Susanto
author_sort	Ngadiwiyana Ngadiwiyana
title	Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate
title_short	Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate
title_full	Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate
title_fullStr	Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate
title_full_unstemmed	Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate
title_sort	synthesis, characterization, and study of proton exchange polymer membrane properties of sulfonated copolymer eugenol-diallyl phthalate
publisher	Department of Chemistry, Universitas Gadjah Mada
publishDate	2020
url	https://doaj.org/article/729c7b47a7f047e683c8bd70cec9409d
work_keys_str_mv	AT ngadiwiyanangadiwiyana synthesischaracterizationandstudyofprotonexchangepolymermembranepropertiesofsulfonatedcopolymereugenoldiallylphthalate AT norbasidadiwibawaprasetya synthesischaracterizationandstudyofprotonexchangepolymermembranepropertiesofsulfonatedcopolymereugenoldiallylphthalate AT gunawangunawan synthesischaracterizationandstudyofprotonexchangepolymermembranepropertiesofsulfonatedcopolymereugenoldiallylphthalate AT tutukdjokokusworo synthesischaracterizationandstudyofprotonexchangepolymermembranepropertiesofsulfonatedcopolymereugenoldiallylphthalate AT herususanto synthesischaracterizationandstudyofprotonexchangepolymermembranepropertiesofsulfonatedcopolymereugenoldiallylphthalate
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Synthesis, Characterization, and Study of Proton Exchange Polymer Membrane Properties of Sulfonated Copolymer Eugenol-diallyl Phthalate

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