Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors

Polymers featuring p-block elements other than carbon are of interest for a range of applications, but access to highly-substituted examples remains challenging. Here the authors demonstrate that cyclic (alkyl)(amino)carbenes can mediate the dehydropolymerisation of phosphine-boranes, leading to the...

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Autores principales:	Nicola L. Oldroyd, Saurabh S. Chitnis, Vincent T. Annibale, Marius I. Arz, Hazel A. Sparkes, Ian Manners
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/729fb92037b84b22b662fcc4843e9b1e
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id	oai:doaj.org-article:729fb92037b84b22b662fcc4843e9b1e
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spelling	oai:doaj.org-article:729fb92037b84b22b662fcc4843e9b1e2021-12-02T15:35:50ZMetal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors10.1038/s41467-019-08967-82041-1723https://doaj.org/article/729fb92037b84b22b662fcc4843e9b1e2019-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-08967-8https://doaj.org/toc/2041-1723Polymers featuring p-block elements other than carbon are of interest for a range of applications, but access to highly-substituted examples remains challenging. Here the authors demonstrate that cyclic (alkyl)(amino)carbenes can mediate the dehydropolymerisation of phosphine-boranes, leading to the construction of P-disubstituted polyphosphinoboranes.Nicola L. OldroydSaurabh S. ChitnisVincent T. AnnibaleMarius I. ArzHazel A. SparkesIan MannersNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Nicola L. Oldroyd Saurabh S. Chitnis Vincent T. Annibale Marius I. Arz Hazel A. Sparkes Ian Manners Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
description	Polymers featuring p-block elements other than carbon are of interest for a range of applications, but access to highly-substituted examples remains challenging. Here the authors demonstrate that cyclic (alkyl)(amino)carbenes can mediate the dehydropolymerisation of phosphine-boranes, leading to the construction of P-disubstituted polyphosphinoboranes.
format	article
author	Nicola L. Oldroyd Saurabh S. Chitnis Vincent T. Annibale Marius I. Arz Hazel A. Sparkes Ian Manners
author_facet	Nicola L. Oldroyd Saurabh S. Chitnis Vincent T. Annibale Marius I. Arz Hazel A. Sparkes Ian Manners
author_sort	Nicola L. Oldroyd
title	Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
title_short	Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
title_full	Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
title_fullStr	Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
title_full_unstemmed	Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
title_sort	metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/729fb92037b84b22b662fcc4843e9b1e
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Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors

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