Ring-opening functionalizations of unstrained cyclic amines enabled by difluorocarbene transfer

Cyclic amines are commonly present in natural products and synthetic compounds, but methods for their skeletal diversification are limited. Here, the authors report a strategy for selective ring-opening functionalization of unstrained cyclic amines to pluripotent products that can be further diversi...

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Autores principales: Youyoung Kim, Joon Heo, Dongwook Kim, Sukbok Chang, Sangwon Seo
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/72ca16811b72489c85e34dc25604f0f7
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Sumario:Cyclic amines are commonly present in natural products and synthetic compounds, but methods for their skeletal diversification are limited. Here, the authors report a strategy for selective ring-opening functionalization of unstrained cyclic amines to pluripotent products that can be further diversified.