Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes

This study explores N–heterocyclic carbene copper complexes toward selective electrocatalytic reduction of acetylene to ethylene. The electron–rich copper sites were found to facilitate acetylene adsorption and ethylene desorption and achieved high activity and selectivity for ethylene production....

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Autores principales:	Lei Zhang, Zhe Chen, Zhenpeng Liu, Jun Bu, Wenxiu Ma, Chen Yan, Rui Bai, Jin Lin, Qiuyu Zhang, Junzhi Liu, Tao Wang, Jian Zhang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/72cb4a08795444c8b48f6484aa2e14de
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spelling	oai:doaj.org-article:72cb4a08795444c8b48f6484aa2e14de2021-11-14T12:35:56ZEfficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes10.1038/s41467-021-26853-02041-1723https://doaj.org/article/72cb4a08795444c8b48f6484aa2e14de2021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26853-0https://doaj.org/toc/2041-1723This study explores N–heterocyclic carbene copper complexes toward selective electrocatalytic reduction of acetylene to ethylene. The electron–rich copper sites were found to facilitate acetylene adsorption and ethylene desorption and achieved high activity and selectivity for ethylene production.Lei ZhangZhe ChenZhenpeng LiuJun BuWenxiu MaChen YanRui BaiJin LinQiuyu ZhangJunzhi LiuTao WangJian ZhangNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Lei Zhang Zhe Chen Zhenpeng Liu Jun Bu Wenxiu Ma Chen Yan Rui Bai Jin Lin Qiuyu Zhang Junzhi Liu Tao Wang Jian Zhang Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes
description	This study explores N–heterocyclic carbene copper complexes toward selective electrocatalytic reduction of acetylene to ethylene. The electron–rich copper sites were found to facilitate acetylene adsorption and ethylene desorption and achieved high activity and selectivity for ethylene production.
format	article
author	Lei Zhang Zhe Chen Zhenpeng Liu Jun Bu Wenxiu Ma Chen Yan Rui Bai Jin Lin Qiuyu Zhang Junzhi Liu Tao Wang Jian Zhang
author_facet	Lei Zhang Zhe Chen Zhenpeng Liu Jun Bu Wenxiu Ma Chen Yan Rui Bai Jin Lin Qiuyu Zhang Junzhi Liu Tao Wang Jian Zhang
author_sort	Lei Zhang
title	Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes
title_short	Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes
title_full	Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes
title_fullStr	Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes
title_full_unstemmed	Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes
title_sort	efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in n–heterocyclic carbene metal complexes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/72cb4a08795444c8b48f6484aa2e14de
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Efficient electrocatalytic acetylene semihydrogenation by electron–rich metal sites in N–heterocyclic carbene metal complexes

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