Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries

Abstract Hydrazine-embedded heterocyclic compounds with dimeric dimethylacridine (1b), carbazole (2b), and phenothiazine (3b) skeletons were applied to cathode active materials of rechargeable lithium organic batteries, and the performance of the batteries was evaluated. The charge/discharge curves...

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Autores principales:	Takeshi Shimizu, Koji Yamamoto, Palash Pandit, Hirofumi Yoshikawa, Shuhei Higashibayashi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/730494160a804b14b69429f49a836938
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spelling	oai:doaj.org-article:730494160a804b14b69429f49a8369382021-12-02T15:08:42ZApplication of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries10.1038/s41598-017-19037-82045-2322https://doaj.org/article/730494160a804b14b69429f49a8369382018-01-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-19037-8https://doaj.org/toc/2045-2322Abstract Hydrazine-embedded heterocyclic compounds with dimeric dimethylacridine (1b), carbazole (2b), and phenothiazine (3b) skeletons were applied to cathode active materials of rechargeable lithium organic batteries, and the performance of the batteries was evaluated. The charge/discharge curves exhibited clear plateaus in the high voltage range of 3.3–3.7 V. The capacities of the plateau regions were comparable to the calculated capacities corresponding to the one-electron redox of the molecules. The amount of the active compound 3b could be increased up to 30 wt% in the electrode composite, and fast charge/discharge performance was also observed.Takeshi ShimizuKoji YamamotoPalash PanditHirofumi YoshikawaShuhei HigashibayashiNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 8, Iss 1, Pp 1-6 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Takeshi Shimizu Koji Yamamoto Palash Pandit Hirofumi Yoshikawa Shuhei Higashibayashi Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
description	Abstract Hydrazine-embedded heterocyclic compounds with dimeric dimethylacridine (1b), carbazole (2b), and phenothiazine (3b) skeletons were applied to cathode active materials of rechargeable lithium organic batteries, and the performance of the batteries was evaluated. The charge/discharge curves exhibited clear plateaus in the high voltage range of 3.3–3.7 V. The capacities of the plateau regions were comparable to the calculated capacities corresponding to the one-electron redox of the molecules. The amount of the active compound 3b could be increased up to 30 wt% in the electrode composite, and fast charge/discharge performance was also observed.
format	article
author	Takeshi Shimizu Koji Yamamoto Palash Pandit Hirofumi Yoshikawa Shuhei Higashibayashi
author_facet	Takeshi Shimizu Koji Yamamoto Palash Pandit Hirofumi Yoshikawa Shuhei Higashibayashi
author_sort	Takeshi Shimizu
title	Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_short	Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_full	Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_fullStr	Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_full_unstemmed	Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries
title_sort	application of hydrazine-embedded heterocyclic compounds to high voltage rechargeable lithium organic batteries
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/730494160a804b14b69429f49a836938
work_keys_str_mv	AT takeshishimizu applicationofhydrazineembeddedheterocycliccompoundstohighvoltagerechargeablelithiumorganicbatteries AT kojiyamamoto applicationofhydrazineembeddedheterocycliccompoundstohighvoltagerechargeablelithiumorganicbatteries AT palashpandit applicationofhydrazineembeddedheterocycliccompoundstohighvoltagerechargeablelithiumorganicbatteries AT hirofumiyoshikawa applicationofhydrazineembeddedheterocycliccompoundstohighvoltagerechargeablelithiumorganicbatteries AT shuheihigashibayashi applicationofhydrazineembeddedheterocycliccompoundstohighvoltagerechargeablelithiumorganicbatteries
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Application of Hydrazine-Embedded Heterocyclic Compounds to High Voltage Rechargeable Lithium Organic Batteries

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