Additive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety

On the basis of a direct current magnetron, a technology has been developed for producing nanoscale-oriented nanorods from zinc oxide on an acrylic polymer. The technology makes it possible to achieve different filling of the surface with zinc oxide nanorods. The nanorods is partially fused into the...

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Autores principales: Dmitry E. Burmistrov, Denis V. Yanykin, Mark O. Paskhin, Egor V. Nagaev, Alexey D. Efimov, Andrey V. Kaziev, Dmitry G. Ageychenkov, Sergey V. Gudkov
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Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/738e9e5f28f1439dbd9781a3fa9f4210
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spelling oai:doaj.org-article:738e9e5f28f1439dbd9781a3fa9f42102021-11-11T18:07:53ZAdditive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety10.3390/ma142165861996-1944https://doaj.org/article/738e9e5f28f1439dbd9781a3fa9f42102021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6586https://doaj.org/toc/1996-1944On the basis of a direct current magnetron, a technology has been developed for producing nanoscale-oriented nanorods from zinc oxide on an acrylic polymer. The technology makes it possible to achieve different filling of the surface with zinc oxide nanorods. The nanorods is partially fused into the polymer; the cross section of the nanorods is rather close to an elongated ellipse. It is shown that, with intense abrasion, no delamination of the nanorods from the acrylic polymer is observed. The zinc oxide nanorods abrades together with the acrylic polymer. Zinc oxide nanorods luminesces with the wavelength most preferable for the process of photosynthesis in higher plants. It was shown that plants grown under the obtained material grow faster and gain biomass faster than the control group. In addition, it was found that on surfaces containing zinc oxide nanorods, a more intense formation of such reactive oxygen species as hydrogen peroxide and hydroxyl radical is observed. Intensive formation of long-lived, active forms of the protein is observed on the zinc oxide coating. The formation of 8-oxoguanine in DNA in vitro on a zinc oxide coating was shown using ELISA method. It was found that the multiplication of microorganisms on the developed material is significantly hampered. At the same time, eukaryotic cells of animals grow and develop without hindrance. Thus, the material we have obtained can be used in photonics (photoconversion material for greenhouses, housings for LEDs), and it is also an affordable and non-toxic nanomaterial for creating antibacterial coatings.Dmitry E. BurmistrovDenis V. YanykinMark O. PaskhinEgor V. NagaevAlexey D. EfimovAndrey V. KazievDmitry G. AgeychenkovSergey V. GudkovMDPI AGarticleZnOreactive magnetron sputteringsputtering in an argon-oxygen mixturephotoconversion materialsagrophotonicsbiocompatibilityTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6586, p 6586 (2021)
institution DOAJ
collection DOAJ
language EN
topic ZnO
reactive magnetron sputtering
sputtering in an argon-oxygen mixture
photoconversion materials
agrophotonics
biocompatibility
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle ZnO
reactive magnetron sputtering
sputtering in an argon-oxygen mixture
photoconversion materials
agrophotonics
biocompatibility
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Dmitry E. Burmistrov
Denis V. Yanykin
Mark O. Paskhin
Egor V. Nagaev
Alexey D. Efimov
Andrey V. Kaziev
Dmitry G. Ageychenkov
Sergey V. Gudkov
Additive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety
description On the basis of a direct current magnetron, a technology has been developed for producing nanoscale-oriented nanorods from zinc oxide on an acrylic polymer. The technology makes it possible to achieve different filling of the surface with zinc oxide nanorods. The nanorods is partially fused into the polymer; the cross section of the nanorods is rather close to an elongated ellipse. It is shown that, with intense abrasion, no delamination of the nanorods from the acrylic polymer is observed. The zinc oxide nanorods abrades together with the acrylic polymer. Zinc oxide nanorods luminesces with the wavelength most preferable for the process of photosynthesis in higher plants. It was shown that plants grown under the obtained material grow faster and gain biomass faster than the control group. In addition, it was found that on surfaces containing zinc oxide nanorods, a more intense formation of such reactive oxygen species as hydrogen peroxide and hydroxyl radical is observed. Intensive formation of long-lived, active forms of the protein is observed on the zinc oxide coating. The formation of 8-oxoguanine in DNA in vitro on a zinc oxide coating was shown using ELISA method. It was found that the multiplication of microorganisms on the developed material is significantly hampered. At the same time, eukaryotic cells of animals grow and develop without hindrance. Thus, the material we have obtained can be used in photonics (photoconversion material for greenhouses, housings for LEDs), and it is also an affordable and non-toxic nanomaterial for creating antibacterial coatings.
format article
author Dmitry E. Burmistrov
Denis V. Yanykin
Mark O. Paskhin
Egor V. Nagaev
Alexey D. Efimov
Andrey V. Kaziev
Dmitry G. Ageychenkov
Sergey V. Gudkov
author_facet Dmitry E. Burmistrov
Denis V. Yanykin
Mark O. Paskhin
Egor V. Nagaev
Alexey D. Efimov
Andrey V. Kaziev
Dmitry G. Ageychenkov
Sergey V. Gudkov
author_sort Dmitry E. Burmistrov
title Additive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety
title_short Additive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety
title_full Additive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety
title_fullStr Additive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety
title_full_unstemmed Additive Production of a Material Based on an Acrylic Polymer with a Nanoscale Layer of Zno Nanorods Deposited Using a Direct Current Magnetron Discharge: Morphology, Photoconversion Properties, and Biosafety
title_sort additive production of a material based on an acrylic polymer with a nanoscale layer of zno nanorods deposited using a direct current magnetron discharge: morphology, photoconversion properties, and biosafety
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/738e9e5f28f1439dbd9781a3fa9f4210
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