Surface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei
The authors aimed to impart the apatite-forming ability to 50 wt% carbon fiber-polyetheretherketone composite (50C-PEEK), which has more suitable mechanical properties as artificial bone materials than pure PEEK. First, the 50C-PEEK was treated with sulfuric acid in a short time to form pores on the...
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MDPI AG
2021
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oai:doaj.org-article:73f2f1216ab74411844a8fffa0670e172021-11-11T18:11:41ZSurface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei10.3390/ma142166911996-1944https://doaj.org/article/73f2f1216ab74411844a8fffa0670e172021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/21/6691https://doaj.org/toc/1996-1944The authors aimed to impart the apatite-forming ability to 50 wt% carbon fiber-polyetheretherketone composite (50C-PEEK), which has more suitable mechanical properties as artificial bone materials than pure PEEK. First, the 50C-PEEK was treated with sulfuric acid in a short time to form pores on the surface. Second, the surface of the 50C-PEEK was treated with oxygen plasma to improve the hydrophilicity. Finally, fine particles of calcium phosphate, which the authors refer to as “apatite nuclei”, were precipitated on the surface of the 50C-PEEK by soaking in an aqueous solution containing multiple inorganic ions such as phosphate and calcium (modified-SBF) at pH 8.20, 25 °C. The 50C-PEEK without the modified-SBF treatment did not show the formation of apatitic phase even after immersion in simulated body fluid (SBF) for 7 days. The 50C-PEEK treated with the modified-SBF showed the formation of apatitic phase on the entire surface within 1 day in the SBF. The apatite nuclei-precipitated 50C-PEEK will be expected as a new artificial bone material with high bioactivity that is obtained without complicated fabrication processes.Yuya YamaneTakeshi YabutsukaYusuke TakaokaChihiro IshizakiShigeomi TakaiShunsuke FujibayashiMDPI AGarticlecarbon fiber-polyetheretherketone compositeapatite nucleiapatite-forming abilitybioactivitysulfuric acid treatmentoxygen plasma treatmentTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6691, p 6691 (2021) |
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carbon fiber-polyetheretherketone composite apatite nuclei apatite-forming ability bioactivity sulfuric acid treatment oxygen plasma treatment Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 |
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carbon fiber-polyetheretherketone composite apatite nuclei apatite-forming ability bioactivity sulfuric acid treatment oxygen plasma treatment Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Yuya Yamane Takeshi Yabutsuka Yusuke Takaoka Chihiro Ishizaki Shigeomi Takai Shunsuke Fujibayashi Surface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei |
description |
The authors aimed to impart the apatite-forming ability to 50 wt% carbon fiber-polyetheretherketone composite (50C-PEEK), which has more suitable mechanical properties as artificial bone materials than pure PEEK. First, the 50C-PEEK was treated with sulfuric acid in a short time to form pores on the surface. Second, the surface of the 50C-PEEK was treated with oxygen plasma to improve the hydrophilicity. Finally, fine particles of calcium phosphate, which the authors refer to as “apatite nuclei”, were precipitated on the surface of the 50C-PEEK by soaking in an aqueous solution containing multiple inorganic ions such as phosphate and calcium (modified-SBF) at pH 8.20, 25 °C. The 50C-PEEK without the modified-SBF treatment did not show the formation of apatitic phase even after immersion in simulated body fluid (SBF) for 7 days. The 50C-PEEK treated with the modified-SBF showed the formation of apatitic phase on the entire surface within 1 day in the SBF. The apatite nuclei-precipitated 50C-PEEK will be expected as a new artificial bone material with high bioactivity that is obtained without complicated fabrication processes. |
format |
article |
author |
Yuya Yamane Takeshi Yabutsuka Yusuke Takaoka Chihiro Ishizaki Shigeomi Takai Shunsuke Fujibayashi |
author_facet |
Yuya Yamane Takeshi Yabutsuka Yusuke Takaoka Chihiro Ishizaki Shigeomi Takai Shunsuke Fujibayashi |
author_sort |
Yuya Yamane |
title |
Surface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei |
title_short |
Surface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei |
title_full |
Surface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei |
title_fullStr |
Surface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei |
title_full_unstemmed |
Surface Modification of Carbon Fiber-Polyetheretherketone Composite to Impart Bioactivity by Using Apatite Nuclei |
title_sort |
surface modification of carbon fiber-polyetheretherketone composite to impart bioactivity by using apatite nuclei |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/73f2f1216ab74411844a8fffa0670e17 |
work_keys_str_mv |
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1718431892608385024 |