Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation

The preparation of superhydrophobic (SH) surface on stainless steel by chemical etching method is challenging due to the good corrosion resistance of the material. In this work, SH surface with water contact angle (WCA) as high as 163.21° was accomplished on 304 stainless steel surface by a rapid ul...

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Autores principales: Zongbo Zhang, Chunling Xu, Wengang Liu, Kai Wang, Yunlong Rao, Chen Jiang, Dawei Li, Yu Zhang, Xin Jiang, Xintong Chen, Changbin Xu
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Lenguaje:EN
Publicado: Elsevier 2021
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Acceso en línea:https://doaj.org/article/73f41c4809704ad9b286823b2dd6ce6f
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spelling oai:doaj.org-article:73f41c4809704ad9b286823b2dd6ce6f2021-11-30T04:14:32ZUltrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation1350-417710.1016/j.ultsonch.2021.105848https://doaj.org/article/73f41c4809704ad9b286823b2dd6ce6f2021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1350417721003904https://doaj.org/toc/1350-4177The preparation of superhydrophobic (SH) surface on stainless steel by chemical etching method is challenging due to the good corrosion resistance of the material. In this work, SH surface with water contact angle (WCA) as high as 163.21° was accomplished on 304 stainless steel surface by a rapid ultrasonic-assisted chemical etching method within 7 min and a low-cost fluorine-free modification treatment. The mechanism of ultrasonic field on the etching process was explored by detecting the cavitation and oscillation energy in the reactor. It is the first time to found that the ultrasonic cavitation effect enhanced the etching process by both chemical and physical facilitation resulting in hierarchical lamellar micro-structures, “mountain-like” micro-structure clusters and “coral-reef-like” nano-scale structures on the surface. With the ultrasonic power increasing, the ultrasonic cavitation effect not only enhanced the superhydrophobicity of sample surface, but also improved the uniformity of surface wettability. The samples also showed excellent performance of oil/water separation for various organics (all separation efficiencies up to 96%) and remarkable mechanical stability.Zongbo ZhangChunling XuWengang LiuKai WangYunlong RaoChen JiangDawei LiYu ZhangXin JiangXintong ChenChangbin XuElsevierarticleStainless steelUltrasoundSuperhydrophobicUltrasonic cavitationUltrasonic vibrationChemistryQD1-999Acoustics. SoundQC221-246ENUltrasonics Sonochemistry, Vol 81, Iss , Pp 105848- (2021)
institution DOAJ
collection DOAJ
language EN
topic Stainless steel
Ultrasound
Superhydrophobic
Ultrasonic cavitation
Ultrasonic vibration
Chemistry
QD1-999
Acoustics. Sound
QC221-246
spellingShingle Stainless steel
Ultrasound
Superhydrophobic
Ultrasonic cavitation
Ultrasonic vibration
Chemistry
QD1-999
Acoustics. Sound
QC221-246
Zongbo Zhang
Chunling Xu
Wengang Liu
Kai Wang
Yunlong Rao
Chen Jiang
Dawei Li
Yu Zhang
Xin Jiang
Xintong Chen
Changbin Xu
Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
description The preparation of superhydrophobic (SH) surface on stainless steel by chemical etching method is challenging due to the good corrosion resistance of the material. In this work, SH surface with water contact angle (WCA) as high as 163.21° was accomplished on 304 stainless steel surface by a rapid ultrasonic-assisted chemical etching method within 7 min and a low-cost fluorine-free modification treatment. The mechanism of ultrasonic field on the etching process was explored by detecting the cavitation and oscillation energy in the reactor. It is the first time to found that the ultrasonic cavitation effect enhanced the etching process by both chemical and physical facilitation resulting in hierarchical lamellar micro-structures, “mountain-like” micro-structure clusters and “coral-reef-like” nano-scale structures on the surface. With the ultrasonic power increasing, the ultrasonic cavitation effect not only enhanced the superhydrophobicity of sample surface, but also improved the uniformity of surface wettability. The samples also showed excellent performance of oil/water separation for various organics (all separation efficiencies up to 96%) and remarkable mechanical stability.
format article
author Zongbo Zhang
Chunling Xu
Wengang Liu
Kai Wang
Yunlong Rao
Chen Jiang
Dawei Li
Yu Zhang
Xin Jiang
Xintong Chen
Changbin Xu
author_facet Zongbo Zhang
Chunling Xu
Wengang Liu
Kai Wang
Yunlong Rao
Chen Jiang
Dawei Li
Yu Zhang
Xin Jiang
Xintong Chen
Changbin Xu
author_sort Zongbo Zhang
title Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
title_short Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
title_full Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
title_fullStr Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
title_full_unstemmed Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
title_sort ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
publisher Elsevier
publishDate 2021
url https://doaj.org/article/73f41c4809704ad9b286823b2dd6ce6f
work_keys_str_mv AT zongbozhang ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT chunlingxu ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT wengangliu ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT kaiwang ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT yunlongrao ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT chenjiang ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT daweili ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT yuzhang ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT xinjiang ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT xintongchen ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
AT changbinxu ultrasonicassistedrapidpreparationofsuperhydrophobicstainlesssteelsurfaceanditsapplicationinoilwaterseparation
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