Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation
The preparation of superhydrophobic (SH) surface on stainless steel by chemical etching method is challenging due to the good corrosion resistance of the material. In this work, SH surface with water contact angle (WCA) as high as 163.21° was accomplished on 304 stainless steel surface by a rapid ul...
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2021
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oai:doaj.org-article:73f41c4809704ad9b286823b2dd6ce6f2021-11-30T04:14:32ZUltrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation1350-417710.1016/j.ultsonch.2021.105848https://doaj.org/article/73f41c4809704ad9b286823b2dd6ce6f2021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1350417721003904https://doaj.org/toc/1350-4177The preparation of superhydrophobic (SH) surface on stainless steel by chemical etching method is challenging due to the good corrosion resistance of the material. In this work, SH surface with water contact angle (WCA) as high as 163.21° was accomplished on 304 stainless steel surface by a rapid ultrasonic-assisted chemical etching method within 7 min and a low-cost fluorine-free modification treatment. The mechanism of ultrasonic field on the etching process was explored by detecting the cavitation and oscillation energy in the reactor. It is the first time to found that the ultrasonic cavitation effect enhanced the etching process by both chemical and physical facilitation resulting in hierarchical lamellar micro-structures, “mountain-like” micro-structure clusters and “coral-reef-like” nano-scale structures on the surface. With the ultrasonic power increasing, the ultrasonic cavitation effect not only enhanced the superhydrophobicity of sample surface, but also improved the uniformity of surface wettability. The samples also showed excellent performance of oil/water separation for various organics (all separation efficiencies up to 96%) and remarkable mechanical stability.Zongbo ZhangChunling XuWengang LiuKai WangYunlong RaoChen JiangDawei LiYu ZhangXin JiangXintong ChenChangbin XuElsevierarticleStainless steelUltrasoundSuperhydrophobicUltrasonic cavitationUltrasonic vibrationChemistryQD1-999Acoustics. SoundQC221-246ENUltrasonics Sonochemistry, Vol 81, Iss , Pp 105848- (2021) |
institution |
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DOAJ |
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EN |
topic |
Stainless steel Ultrasound Superhydrophobic Ultrasonic cavitation Ultrasonic vibration Chemistry QD1-999 Acoustics. Sound QC221-246 |
spellingShingle |
Stainless steel Ultrasound Superhydrophobic Ultrasonic cavitation Ultrasonic vibration Chemistry QD1-999 Acoustics. Sound QC221-246 Zongbo Zhang Chunling Xu Wengang Liu Kai Wang Yunlong Rao Chen Jiang Dawei Li Yu Zhang Xin Jiang Xintong Chen Changbin Xu Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation |
description |
The preparation of superhydrophobic (SH) surface on stainless steel by chemical etching method is challenging due to the good corrosion resistance of the material. In this work, SH surface with water contact angle (WCA) as high as 163.21° was accomplished on 304 stainless steel surface by a rapid ultrasonic-assisted chemical etching method within 7 min and a low-cost fluorine-free modification treatment. The mechanism of ultrasonic field on the etching process was explored by detecting the cavitation and oscillation energy in the reactor. It is the first time to found that the ultrasonic cavitation effect enhanced the etching process by both chemical and physical facilitation resulting in hierarchical lamellar micro-structures, “mountain-like” micro-structure clusters and “coral-reef-like” nano-scale structures on the surface. With the ultrasonic power increasing, the ultrasonic cavitation effect not only enhanced the superhydrophobicity of sample surface, but also improved the uniformity of surface wettability. The samples also showed excellent performance of oil/water separation for various organics (all separation efficiencies up to 96%) and remarkable mechanical stability. |
format |
article |
author |
Zongbo Zhang Chunling Xu Wengang Liu Kai Wang Yunlong Rao Chen Jiang Dawei Li Yu Zhang Xin Jiang Xintong Chen Changbin Xu |
author_facet |
Zongbo Zhang Chunling Xu Wengang Liu Kai Wang Yunlong Rao Chen Jiang Dawei Li Yu Zhang Xin Jiang Xintong Chen Changbin Xu |
author_sort |
Zongbo Zhang |
title |
Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation |
title_short |
Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation |
title_full |
Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation |
title_fullStr |
Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation |
title_full_unstemmed |
Ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation |
title_sort |
ultrasonic assisted rapid preparation of superhydrophobic stainless steel surface and its application in oil/water separation |
publisher |
Elsevier |
publishDate |
2021 |
url |
https://doaj.org/article/73f41c4809704ad9b286823b2dd6ce6f |
work_keys_str_mv |
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1718406810296123392 |