Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process

Sawdust is usually considered as waste in wood-using industries. These materials can be converted into value added thermoplastics by means of benzylation. Products can be utilized in different applications where plastics are used. Thermoplasticization process was carried out with benzyl chloride und...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Birol Üner, Gökhan Köse, Yeşim Yürümez, Ömer Ümit Yalçın, Mehmet Akgül
Formato:	article
Lenguaje:	EN
Publicado:	University of Zagreb, Faculty of Forestry and Wood Technology 2017
Materias:	thermoplastic resin hydrogen bond energy crystallinity thermal properties Forestry SD1-669.5
Acceso en línea:	https://doaj.org/article/743bbc8b53ce4cddbb7ea76736aed8b2
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:743bbc8b53ce4cddbb7ea76736aed8b2
record_format	dspace
spelling	oai:doaj.org-article:743bbc8b53ce4cddbb7ea76736aed8b22021-12-02T07:24:06ZWood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process10.5552/drind.2016.15340012-67721847-1153https://doaj.org/article/743bbc8b53ce4cddbb7ea76736aed8b22017-01-01T00:00:00Zhttp://hrcak.srce.hr/172519https://doaj.org/toc/0012-6772https://doaj.org/toc/1847-1153Sawdust is usually considered as waste in wood-using industries. These materials can be converted into value added thermoplastics by means of benzylation. Products can be utilized in different applications where plastics are used. Thermoplasticization process was carried out with benzyl chloride under different alkaline conditions, 15, 25 and 35 %, respectively. Alkali ions and concentration affect the substitution reaction. Tailored material structure was remarkably changed. In order to detect changes, crystallinity index of the materials and thermal properties were analyzed. In FTIR spectra, the peaks appeared at 698 cm-1 and 740 cm-1, which indicates the aromatic C-C angular deformation. Multiple peak appears at 3030 cm-1, which indicates benzylation of the materials. The peak increase can be observed at 1596 cm-1 due to the aromatic deformation. Benzyl groups attached to hydroxyl to form ether groups increase the peak intensity. As a result of that, hydrogen bond energy changes and crystallinity of the materials is reduced. This substitution of functional groups changes the decomposition temperature of modified materials. It reduces the decomposition temperature to between 330 and 350 ºC. Thermogravimetric analysis revealed that modified products were characterized by poorer thermal stability compared to raw materials.Birol ÜnerGökhan KöseYeşim YürümezÖmer Ümit YalçınMehmet AkgülUniversity of Zagreb, Faculty of Forestry and Wood Technologyarticlethermoplastic resinhydrogen bond energycrystallinitythermal propertiesForestrySD1-669.5ENDrvna Industrija, Vol 67, Iss 4, Pp 315-322 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	thermoplastic resin hydrogen bond energy crystallinity thermal properties Forestry SD1-669.5
spellingShingle	thermoplastic resin hydrogen bond energy crystallinity thermal properties Forestry SD1-669.5 Birol Üner Gökhan Köse Yeşim Yürümez Ömer Ümit Yalçın Mehmet Akgül Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process
description	Sawdust is usually considered as waste in wood-using industries. These materials can be converted into value added thermoplastics by means of benzylation. Products can be utilized in different applications where plastics are used. Thermoplasticization process was carried out with benzyl chloride under different alkaline conditions, 15, 25 and 35 %, respectively. Alkali ions and concentration affect the substitution reaction. Tailored material structure was remarkably changed. In order to detect changes, crystallinity index of the materials and thermal properties were analyzed. In FTIR spectra, the peaks appeared at 698 cm-1 and 740 cm-1, which indicates the aromatic C-C angular deformation. Multiple peak appears at 3030 cm-1, which indicates benzylation of the materials. The peak increase can be observed at 1596 cm-1 due to the aromatic deformation. Benzyl groups attached to hydroxyl to form ether groups increase the peak intensity. As a result of that, hydrogen bond energy changes and crystallinity of the materials is reduced. This substitution of functional groups changes the decomposition temperature of modified materials. It reduces the decomposition temperature to between 330 and 350 ºC. Thermogravimetric analysis revealed that modified products were characterized by poorer thermal stability compared to raw materials.
format	article
author	Birol Üner Gökhan Köse Yeşim Yürümez Ömer Ümit Yalçın Mehmet Akgül
author_facet	Birol Üner Gökhan Köse Yeşim Yürümez Ömer Ümit Yalçın Mehmet Akgül
author_sort	Birol Üner
title	Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process
title_short	Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process
title_full	Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process
title_fullStr	Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process
title_full_unstemmed	Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process
title_sort	wood waste turned into value added products: thermal plasticization by benzylation process
publisher	University of Zagreb, Faculty of Forestry and Wood Technology
publishDate	2017
url	https://doaj.org/article/743bbc8b53ce4cddbb7ea76736aed8b2
work_keys_str_mv	AT biroluner woodwasteturnedintovalueaddedproductsthermalplasticizationbybenzylationprocess AT gokhankose woodwasteturnedintovalueaddedproductsthermalplasticizationbybenzylationprocess AT yesimyurumez woodwasteturnedintovalueaddedproductsthermalplasticizationbybenzylationprocess AT omerumityalcın woodwasteturnedintovalueaddedproductsthermalplasticizationbybenzylationprocess AT mehmetakgul woodwasteturnedintovalueaddedproductsthermalplasticizationbybenzylationprocess
_version_	1718399461396316160

Wood Waste Turned Into Value Added Products: Thermal Plasticization by Benzylation Process

Ejemplares similares