Asymmetric radical carboesterification of dienes

Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands, likely proceeding via an allylic radical.

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Detalles Bibliográficos
Autores principales: Xiaotao Zhu, Wujun Jian, Meirong Huang, Daliang Li, Yajun Li, Xinhao Zhang, Hongli Bao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/74d521cbe079484385515794b20060c0
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Descripción
Sumario:Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands, likely proceeding via an allylic radical.