Asymmetric radical carboesterification of dienes

Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands, likely proceeding via an allylic radical.

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Autores principales:	Xiaotao Zhu, Wujun Jian, Meirong Huang, Daliang Li, Yajun Li, Xinhao Zhang, Hongli Bao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/74d521cbe079484385515794b20060c0
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spelling	oai:doaj.org-article:74d521cbe079484385515794b20060c02021-11-21T12:34:25ZAsymmetric radical carboesterification of dienes10.1038/s41467-021-26843-22041-1723https://doaj.org/article/74d521cbe079484385515794b20060c02021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-26843-2https://doaj.org/toc/2041-1723Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands, likely proceeding via an allylic radical.Xiaotao ZhuWujun JianMeirong HuangDaliang LiYajun LiXinhao ZhangHongli BaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xiaotao Zhu Wujun Jian Meirong Huang Daliang Li Yajun Li Xinhao Zhang Hongli Bao Asymmetric radical carboesterification of dienes
description	Stereocontrol of C–O bond formation from a carbon-based radical is very difficult due to the rapid inversion of the carbon radical. Here the authors present a method to form chiral esters from conjugated dienes with copper and chiral PyBox ligands, likely proceeding via an allylic radical.
format	article
author	Xiaotao Zhu Wujun Jian Meirong Huang Daliang Li Yajun Li Xinhao Zhang Hongli Bao
author_facet	Xiaotao Zhu Wujun Jian Meirong Huang Daliang Li Yajun Li Xinhao Zhang Hongli Bao
author_sort	Xiaotao Zhu
title	Asymmetric radical carboesterification of dienes
title_short	Asymmetric radical carboesterification of dienes
title_full	Asymmetric radical carboesterification of dienes
title_fullStr	Asymmetric radical carboesterification of dienes
title_full_unstemmed	Asymmetric radical carboesterification of dienes
title_sort	asymmetric radical carboesterification of dienes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/74d521cbe079484385515794b20060c0
work_keys_str_mv	AT xiaotaozhu asymmetricradicalcarboesterificationofdienes AT wujunjian asymmetricradicalcarboesterificationofdienes AT meironghuang asymmetricradicalcarboesterificationofdienes AT daliangli asymmetricradicalcarboesterificationofdienes AT yajunli asymmetricradicalcarboesterificationofdienes AT xinhaozhang asymmetricradicalcarboesterificationofdienes AT honglibao asymmetricradicalcarboesterificationofdienes
_version_	1718418891591385088

Asymmetric radical carboesterification of dienes

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