Hydrogen spillover through Matryoshka-type (ZIFs@) n−1ZIFs nanocubes

Hydrogen spillover is well-documented in hydrogenation catalysis, but its existence through metalorganic frameworks (MOFs) remains controversial. Here, the authors provide evidence of the occurrence of hydrogen spillover in microporous MOFs at elevated temperatures, and measure quantitatively the pe...

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Auteurs principaux: Guowu Zhan, Hua Chun Zeng
Format: article
Langue:EN
Publié: Nature Portfolio 2018
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Accès en ligne:https://doaj.org/article/759b5ba96519428e9683c8bc9f58d66d
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Résumé:Hydrogen spillover is well-documented in hydrogenation catalysis, but its existence through metalorganic frameworks (MOFs) remains controversial. Here, the authors provide evidence of the occurrence of hydrogen spillover in microporous MOFs at elevated temperatures, and measure quantitatively the penetration depths of atomic hydrogen.